Electrosynthetic C− O bond activation in alcohols and alcohol derivatives

P Villo, A Shatskiy, MD Kärkäs… - Angewandte Chemie …, 2023 - Wiley Online Library
Alcohols and their derivatives are ubiquitous and versatile motifs in organic synthesis.
Deoxygenative transformations of these compounds are often challenging due to the …

Electrosynthesis using carboxylic acid derivatives: new tricks for old reactions

MC Leech, K Lam - Accounts of Chemical Research, 2020 - ACS Publications
Conspectus Electrosynthetic organic chemistry is an old discipline that takes its root in
Faraday's seminal works. The field has a rich history and is in the midst of a renaissance …

[图书][B] Organic electrochemistry

O Hammerich, B Speiser - 2016 - api.taylorfrancis.com
Organic electrochemistry is concerned with the reduction and oxidation of organic molecules
at electrodes. Although it is now more than 200 years ago that the so-called Volta pile was …

Homogeneous electron transfer catalysis of the electrochemical reduction of carbon dioxide. Do aromatic anion radicals react in an outer-sphere manner?

A Gennaro, AA Isse, JM Savéant… - Journal of the …, 1996 - ACS Publications
Electrochemically generated anion radicals of aromatic nitriles and esters possess the
remarkable property to reduce carbon dioxide to oxalate with negligible formation of …

Using toluates as simple and versatile radical precursors

K Lam, IE Markó - Organic letters, 2008 - ACS Publications
Using Toluates as Simple and Versatile Radical Precursors | Organic Letters ACS ACS
Publications C&EN CAS Find my institution Log In Organic Letters ACS Publications. Most …

Novel electrochemical deoxygenation reaction using diphenylphosphinates

K Lam, IE Markó - Organic letters, 2011 - ACS Publications
The electrochemical reduction of diphenylphosphinate esters leads smoothly and in high
yields to the corresponding deoxygenated products. In comparison with the previously …

С-ОН bond cleavage initiated by electron transfer: electroreduction of 9-fluorenol

AS Mendkovich, MA Syroeshkin, DV Nasybullina… - Electrochimica …, 2016 - Elsevier
Сyclic voltammetry, chronoamperometry, coulometry, electrolysis, digital simulation,
quantum chemical calculations of 9-fluorenol as an example, were used to show that the …

Toluates: unexpectedly versatile reagents

K Lam, IE Markó - Tetrahedron, 2009 - Elsevier
The mechanism of the monoelectronic reduction of aromatic esters has been investigated.
The unexpected synthetic utility of the toluate moiety in the deoxygenation of alcohols and …

Electrochemical reduction of some 2, 6-disubstituted pyridine-based esters and thioic S-esters in acetonitrile

RD Webster, AM Bond, T Schmidt - Journal of the Chemical Society …, 1995 - pubs.rsc.org
Voltammetric studies at glassy carbon, gold, mercury, platinum and silver electrodes on 2, 6-
disubstituted pyridine esters and thioic S-esters in acetonitrile have shown that they may be …

Electrochemical Reduction of Pyridine- and Benzene-Substituted n-Alkyl Esters and Thioic S-Esters in Acetonitrile

RD Webster, AM Bond - The Journal of Organic Chemistry, 1997 - ACS Publications
Bulk controlled potential electrolysis experiments have been performed on a wide range of n-
alkyl-substituted esters and thioic S-esters of pyridine and benzene in dry acetonitrile with …