Actinide metal-organic frameworks (An-MOFs) consisting of actinide nodes and organic
linkers represent an underexplored category of coordination polymers due to challenges in …

The significant interest in actinide bonding has recently focused on novel compounds with
exotic oxidation states. However, the difficulty in obtaining relevant high-quality experimental …

FEUDAL (f's essentially unaffected, d's accommodate ligands) is a longstanding bonding
model in actinide chemistry, in which metal-ligand binding uses 6d-orbitals, with the 5f …

Crystalline coordination complexes of actinides, especially in atypical oxidation states, are
not only fundamentally important for expanding the notably limited knowledge on the …

Using a redox-active dioxophenoxazine ligand, DOPO (DOPO= 2, 4, 6, 8-tetra-tert-butyl-1-
oxo-1 H-phenoxazine-9-olate), a family of actinide (U, Th, Np, and Pu) and Hf tris (ligand) …

Despite the fact that non-aqueous uranium chemistry is over 60 years old, most polarised-
covalent uranium-element multiple bonds involve formal uranium oxidation states IV, V, and …

Lanthanides such as europium with more accessible divalent states are useful for studying
redox stability afforded by macrocyclic organic ligands. Substituted cryptands, such as 2.2 …

Variations in bonding between trivalent lanthanides and actinides is critical for reprocessing
spent nuclear fuel. The ability to tune bonding and the coordination environment in these …

On the basis of a recent report by Deng et al. in Nature Communications, we have identified
the origin of the quite different behaviors of isostructural Ni (OH) 2 and Co (OH) 2 as …

Comprehensive Summary The second example of tetravalent plutonium carboxyl‐based
organic framework, 242Pu (OH)[PO [(C6H4) COO] 3]· H2O, termed as PuTPO (TPO= tris (4 …