Surface restructuring and predictive design of heterogeneous catalysts

F Tao, M Salmeron - Science, 2024 - science.org
Heterogeneous catalysts, which often consist of metal nanoparticles loaded on supports
such as metal oxides, can undergo several types of restructuring under reaction and …

Lab-based ambient pressure X-ray photoelectron spectroscopy from past to present

C Arble, M Jia, JT Newberg - Surface Science Reports, 2018 - Elsevier
Chemical interactions which occur at a heterogeneous interface between a gas and
substrate are critical in many technological and natural processes. Ambient pressure X-ray …

Twin boundary migration in an individual platinum nanocrystal during catalytic CO oxidation

J Carnis, AR Kshirsagar, L Wu, M Dupraz… - Nature …, 2021 - nature.com
At the nanoscale, elastic strain and crystal defects largely influence the properties and
functionalities of materials. The ability to predict the structural evolution of catalytic …

Interplay between CO Disproportionation and Oxidation: On the Origin of the CO Reaction Onset on Atomic Layer Deposition-Grown Pt/ZrO2 Model Catalysts

V Pramhaas, M Roiaz, N Bosio, M Corva… - ACS …, 2020 - ACS Publications
Pt/ZrO2 model catalysts were prepared by atomic layer deposition (ALD) and examined at
mbar pressure by operando sum frequency generation (SFG) spectroscopy and near …

[HTML][HTML] Surface science approach to Pt/carbon model catalysts: XPS, STM and microreactor studies

AM Motin, T Haunold, AV Bukhtiyarov, A Bera… - Applied Surface …, 2018 - Elsevier
Pt nanoparticles supported on carbon are an important technological catalyst. A
corresponding model catalyst was prepared by physical vapor deposition (PVD) of Pt on …

Probing active sites on Pd/Pt alloy nanoparticles by CO adsorption

DS Dolling, J Chen, JC Schober, M Creutzburg… - ACS …, 2024 - ACS Publications
We studied the adsorption of CO on Pd/Pt nanoparticles (NPs) with varying compositions
using polarization-dependent Fourier transform infrared reflection absorption spectroscopy …

[HTML][HTML] Sum frequency generation (SFG) spectroscopy at surfaces and interfaces: Adsorbate structure and molecular bond orientation

X Li, G Rupprechter - Surface Science Reports, 2024 - Elsevier
Abstract Infrared (IR)-visible (Vis) sum frequency generation (SFG) is a second-order
nonlinear optical process which is forbidden in centrosymmetric bulk media or isotropic …

Tailoring the electronic states of Pt by atomic layer deposition of Al2O3 for enhanced CO oxidation performance: Experimental and theoretical investigations

S Hu, M Huang, J Li, J He, K Xu, X Rao, D Cai… - Applied Catalysis B …, 2023 - Elsevier
Herein, atomic layer deposition (ALD)-Al 2 O 3 films were applied as a medium to modulate
the electronic states of the supported Pt. Based on the sacrificial template of ZIF-67, the …

Roughening of copper (100) at elevated CO pressure: Cu adatom and cluster formation enable CO dissociation

M Roiaz, L Falivene, C Rameshan… - The Journal of …, 2018 - ACS Publications
Carbon monoxide participates in many copper-catalyzed reactions, which makes CO-
induced structural changes of Cu catalysts key for important industrial processes. We have …

CeO2-Promoted PtSn/SiO2 as a High-Performance Catalyst for the Oxidative Dehydrogenation of Propane with Carbon Dioxide

L Wang, GQ Yang, X Ren, ZW Liu - Nanomaterials, 2022 - mdpi.com
The oxidative dehydrogenation of propane with CO2 (CO2-ODP) has been extensively
investigated as a promising green technology for the efficient production of propylene, but …