Nature‐Inspired Electrocatalysts for CO2 Reduction to C2+ Products
L Xu, P Trogadas, MO Coppens - Advanced Energy Materials, 2023 - Wiley Online Library
The electrocatalytic reduction reaction of carbon dioxide (CO2RR) has gained significant
attention as a promising approach to mitigate carbon dioxide emissions and generate …
attention as a promising approach to mitigate carbon dioxide emissions and generate …
Two-dimensional conductive metal-organic frameworks electrocatalyst: Design principle and energy conversion applications
Designing conductive electrocatalysts for converting energy into value-added chemicals and
fuels offers a promising pathway to attaining a sustainable carbon energy cycle. Concerning …
fuels offers a promising pathway to attaining a sustainable carbon energy cycle. Concerning …
Templating Bicarbonate in the Second Coordination Sphere Enhances Electrochemical CO2 Reduction Catalyzed by Iron Porphyrins
Bicarbonate-based electrolytes are ubiquitous in aqueous electrochemical CO2 reduction,
particularly in heterogenous catalysis, where they demonstrate improved catalytic …
particularly in heterogenous catalysis, where they demonstrate improved catalytic …
Molecular Design Principles to Elongate the Metal-to-Ligand Charge Transfer Excited-State Lifetimes of Square-Planar Nickel (II) Complexes
Square-planar NiII complexes and their electronically excited states play key roles in cross-
coupling catalysis and could offer new opportunities to complement well-known …
coupling catalysis and could offer new opportunities to complement well-known …
Hydrogen-bond-acceptor ligands enable distal C(sp3)–H arylation of free alcohols
The functionalization of C–H bonds in organic molecules is one of the most direct
approaches for chemical synthesis. Recent advances in catalysis have allowed native …
approaches for chemical synthesis. Recent advances in catalysis have allowed native …
Second Coordination Sphere Effect Shifts CO2 to CO Reduction by Iron Porphyrin from Fe0 to FeI
Iron porphyrins are among the most studied molecular catalysts for carbon dioxide (CO2)
reduction and their reactivity is constantly being enhanced through the implementation of …
reduction and their reactivity is constantly being enhanced through the implementation of …
Diastereoselective Self‐Assembly of Low‐Symmetry PdnL2n Nanocages through Coordination‐Sphere Engineering**
Metal‐organic cages (MOCs) are popular host architectures assembled from ligands and
metal ions/nodes. Assembling structurally complex, low‐symmetry MOCs with anisotropic …
metal ions/nodes. Assembling structurally complex, low‐symmetry MOCs with anisotropic …
A Borane Lewis Acid in the Secondary Coordination Sphere of a Ni (II) Imido Imparts Distinct C–H Activation Selectivity
B Wang, CSG Seo, C Zhang, J Chu… - Journal of the …, 2022 - ACS Publications
Two borane-functionalized bidentate phosphine ligands that vary in tether length have been
prepared to examine cooperative metal–substrate interactions. Ni (0) complexes react with …
prepared to examine cooperative metal–substrate interactions. Ni (0) complexes react with …
Counterion Variation: A Useful Lever for Maximizing the Regioselectivity in the Hydroboration of Terminal Alkynes
A Martínez-Bascuñana, JL Núñez-Rico, L Carreras… - ACS …, 2023 - ACS Publications
The role of the counterion in metal-catalyzed reactions can be crucial as this often-
unconsidered component of the catalyst can modify the performance of the catalyst and …
unconsidered component of the catalyst can modify the performance of the catalyst and …
Base metal chemistry and catalysis
ML Clapson, CS Durfy, D Facchinato… - Cell Reports Physical …, 2023 - cell.com
This perspective provides an entry-level conversation concerning base metal catalysis as a
green and sustainable solution in industrial and academic contexts. We establish a …
green and sustainable solution in industrial and academic contexts. We establish a …