Electro-and solar-driven fuel synthesis with first row transition metal complexes

KE Dalle, J Warnan, JJ Leung, B Reuillard… - Chemical …, 2019 - ACS Publications
The synthesis of renewable fuels from abundant water or the greenhouse gas CO2 is a
major step toward creating sustainable and scalable energy storage technologies. In the last …

Transition Metal Complexes as Catalysts for the Electroconversion of CO2: An Organometallic Perspective

NW Kinzel, C Werlé, W Leitner - … Chemie International Edition, 2021 - Wiley Online Library
The electrocatalytic transformation of carbon dioxide has been a topic of interest in the field
of CO2 utilization for a long time. Recently, the area has seen increasing dynamics as an …

Homogeneously catalyzed electroreduction of carbon dioxide—methods, mechanisms, and catalysts

R Francke, B Schille, M Roemelt - Chemical reviews, 2018 - ACS Publications
The utilization of CO2 via electrochemical reduction constitutes a promising approach
toward production of value-added chemicals or fuels using intermittent renewable energy …

Electrons, Photons, Protons and Earth-Abundant Metal Complexes for Molecular Catalysis of CO2 Reduction

H Takeda, C Cometto, O Ishitani, M Robert - Acs Catalysis, 2017 - ACS Publications
Electrochemical and photochemical reduction of CO2, or a smart combination of both, are
appealing approaches for the storage of renewable, intermittent energies and may lead to …

Turning on the Protonation-First Pathway for Electrocatalytic CO2 Reduction by Manganese Bipyridyl Tricarbonyl Complexes

KT Ngo, M McKinnon, B Mahanti… - Journal of the …, 2017 - ACS Publications
Electrocatalytic reduction of CO2 to CO is reported for the complex,{fac-MnI ([(MeO) 2Ph]
2bpy)(CO) 3 (CH3CN)}(OTf), containing four pendant methoxy groups, where [(MeO) 2Ph] …

Mechanistic aspects of CO2 reduction catalysis with manganese-based molecular catalysts

DC Grills, MZ Ertem, M McKinnon, KT Ngo… - Coordination Chemistry …, 2018 - Elsevier
One approach for the conversion of CO 2 into fuels or fuel precursors is the proton-coupled
reduction of CO 2 to CO or formic acid, using transition metal complexes as catalysts in …

Research Progress in Conversion of CO2 to Valuable Fuels

L Xu, Y Xiu, F Liu, Y Liang, S Wang - Molecules, 2020 - mdpi.com
Rapid growth in the world's economy depends on a significant increase in energy
consumption. As is known, most of the present energy supply comes from coal, oil, and …

Molecular catalysts for CO2 Electroreduction: Progress and prospects with pincer type complexes

HA Younus, N Ahmad, W Ni, X Wang, M Al-Abri… - Coordination Chemistry …, 2023 - Elsevier
Transforming wastes or hazardous materials into value-added chemical products is of great
concern from economic, environmental, and sustainable prospects. Various approaches …

A Highly Active N‐Heterocyclic Carbene Manganese(I) Complex for Selective Electrocatalytic CO2 Reduction to CO

F Franco, MF Pinto, B Royo… - Angewandte Chemie, 2018 - Wiley Online Library
We report here the first purely organometallic fac‐[MnI (CO) 3 (bis‐MeNHC) Br] complex with
unprecedented activity for the selective electrocatalytic reduction of CO2 to CO, exceeding …

Non-noble metal-based molecular complexes for CO2 reduction: From the ligand design perspective

DC Liu, DC Zhong, TB Lu - EnergyChem, 2020 - Elsevier
Molecular catalysts for electrochemical and photochemical CO 2 reduction have developed
rapidly during the past two decades. Using non-noble metal (Ni, Co, Mn, Fe, and Cu) …