A novel pincer ligand, iPrPNPhP [PhN (CH2CH2PiPr2) 2], which is an analogue of the
versatile MACHO ligand, iPrPNHP [HN (CH2CH2PiPr2) 2], was synthesized and …

We systematically investigated iodine–metal and iodine–iodine bonding in van Koten's
pincer complex and 19 modifications changing substituents and/or the transition metal with a …

The synthesis of a series of Fe, Co, and Ni complexes supported by an iPrPNPhP
(iPrPNPhP= PhN (CH2CH2PiPr2) 2) pincer ligand is described. These complexes were …

Iron complexes supported by pincer ligands of the type R'N (CH2CH2PR2) 2 (RPNR'P) are
highly active catalysts for a range of hydrogenation and dehydrogenation reactions but are …

The CMD/AMLA mechanisms of cyclopalladation and the parent fictitious but challenging
cyclonickelation of N, N-dimethylbenzylamine have been investigated by joint DFT-D and …

A proximity enforcing diarylsilane ligand is reported, which gives rise to unusual Si–H··· M
interactions with the d10 metal ions Cu+ and Ag+ upon complexation. These interactions are …

Abstraction of chloride from a six-coordinate complex, trans-[Ir (H)(Cl)(iPr) 4
(POCOP)(PPh3)](1)[(iPr) 4 (POCOP)= 2, 6-bis (di-iso-propylphosphinito) benzene, κ3-C6H3 …

Abstract Reaction of bis (2-(diphenylphosphino) ethyl) benzylamine (PNP) and bis (2-
methylpyridyl) benzylamine (NNN) with known closo-ruthenacarborane [3-H-3-Cl-3, 3 …

Treatment of trans-[Ir (H)(N) 2 (iPr) 4 (POCOP)(DMAP)][BAr4f](2) with H2 (1 bar) under
ambient conditions (298 K) results in the formation of a trans-[Ir (H)(η2-H2)(iPr) 4 …

The incorporation of a PPC donor ligand set onto nickel is described. While C–H activation
routes using Ni (II) precursors and benzyl-and phenethyl-substituted diphosphines …