Electrocatalysis in alkaline media and alkaline membrane-based energy technologies

Y Yang, CR Peltier, R Zeng, R Schimmenti, Q Li… - Chemical …, 2022 - ACS Publications
Hydrogen energy-based electrochemical energy conversion technologies offer the promise
of enabling a transition of the global energy landscape from fossil fuels to renewable energy …

Chemomechanics of rechargeable batteries: status, theories, and perspectives

LS de Vasconcelos, R Xu, Z Xu, J Zhang… - Chemical …, 2022 - ACS Publications
Chemomechanics is an old subject, yet its importance has been revived in rechargeable
batteries where the mechanical energy and damage associated with redox reactions can …

Origin of structural degradation in Li-rich layered oxide cathode

T Liu, J Liu, L Li, L Yu, J Diao, T Zhou, S Li, A Dai… - Nature, 2022 - nature.com
Li-and Mn-rich (LMR) cathode materials that utilize both cation and anion redox can yield
substantial increases in battery energy density,–. However, although voltage decay issues …

Strain-retardant coherent perovskite phase stabilized Ni-rich cathode

L Wang, T Liu, T Wu, J Lu - Nature, 2022 - nature.com
The use of state-of-the-art Ni-rich layered oxides (LiNi x Co y Mn1− x− y O2, x> 0.5) as the
cathode material for lithium-ion batteries can push the energy and power density to a higher …

Challenges and recent advances in high capacity Li‐rich cathode materials for high energy density lithium‐ion batteries

W He, W Guo, H Wu, L Lin, Q Liu, X Han… - Advanced …, 2021 - Wiley Online Library
Li‐rich cathode materials have attracted increasing attention because of their high reversible
discharge capacity (> 250 mA hg− 1), which originates from transition metal (TM) ion redox …

Oxygen loss in layered oxide cathodes for Li-ion batteries: Mechanisms, effects, and mitigation

H Zhang, H Liu, LFJ Piper, MS Whittingham… - Chemical …, 2022 - ACS Publications
Layered lithium transition metal oxides derived from LiMO2 (M= Co, Ni, Mn, etc.) have been
widely adopted as the cathodes of Li-ion batteries for portable electronics, electric vehicles …

Cobalt‐free cathode materials: families and their prospects

H Zhao, WYA Lam, L Sheng, L Wang… - Advanced Energy …, 2022 - Wiley Online Library
With the rapid growth of global electro‐mobility, the demand for cobalt is rapidly increasing
because it is currently an indispensable component of the cathode materials in lithium‐ion …

Pushing the limit of 3d transition metal-based layered oxides that use both cation and anion redox for energy storage

M Zhang, DA Kitchaev, Z Lebens-Higgins… - Nature Reviews …, 2022 - nature.com
Intercalation chemistry has dominated electrochemical energy storage for decades, and
storage capacity worldwide has now reached the terawatt-hour level. State-of-the-art …

A materials perspective on direct recycling of lithium‐ion batteries: principles, challenges and opportunities

P Xu, DHS Tan, B Jiao, H Gao, X Yu… - Advanced Functional …, 2023 - Wiley Online Library
As the dominant means of energy storage technology today, the widespread deployment of
lithium‐ion batteries (LIBs) would inevitably generate countless spent batteries at their end …

First-cycle voltage hysteresis in Li-rich 3d cathodes associated with molecular O2 trapped in the bulk

RA House, GJ Rees, MA Pérez-Osorio, JJ Marie… - Nature Energy, 2020 - nature.com
Li-rich cathode materials are potential candidates for next-generation Li-ion batteries.
However, they exhibit a large voltage hysteresis on the first charge/discharge cycle, which …