Organofluorine chemistry: Promising growth areas and challenges

LV Politanskaya, GA Selivanova… - Russian Chemical …, 2019 - iopscience.iop.org
Currently, the chemistry of organofluorine compounds is a leading and rapidly developing
area of organic chemistry. Fluorine present in a molecule largely determines its specific …

Mixed AggregAte (MAA): A single concept for all dipolar organometallic aggregates. 2. Syntheses and reactivities of homo/heteroMAAs

F Mongin, A Harrison-Marchand - Chemical Reviews, 2013 - ACS Publications
Mixing two organometallic reagents leads to synergic mixed aggregates or ate complexes
for which we suggest (as well as for oligomers) the name “Mixed AggregAte” or MAA. The …

Palladium-catalyzed oxidative amination of alkenes: improved catalyst reoxidation enables the use of alkene as the limiting reagent

MM Rogers, V Kotov, J Chatwichien, SS Stahl - Organic Letters, 2007 - ACS Publications
Palladium-catalyzed methods for intermolecular aerobic oxidative amination of alkenes
have been identified that are compatible with the use of alkene as the limiting reagent …

Development of a Concise Synthesis of (−)‐Oseltamivir (Tamiflu)

BM Trost, T Zhang - Chemistry–A European Journal, 2011 - Wiley Online Library
We report a full account of our work towards the development of an eight‐step synthesis of
anti‐influenza drug (−)‐oseltamivir (Tamiflu) from commercially available starting materials …

Dimerization and isomerization reactions of α-lithiated terminal aziridines

DM Hodgson, PG Humphreys, SM Miles… - The Journal of …, 2007 - ACS Publications
The scope of dimerization and isomerization reactions of α-lithiated terminal aziridines is
detailed. Regio-and stereoselective deprotonation of simple terminal aziridines with lithium …

Efficient and mild method for preparation of allylic amines from aziridine-2-alcohols using PPh3/I2/imidazole

SP Chavan, LB Khairnar, PN Chavan - Tetrahedron Letters, 2014 - Elsevier
Efficient and mild method for preparation of allylic amines from aziridine-2-alcohols using
PPh3/I2/imidazole - ScienceDirect Skip to main contentSkip to article Elsevier logo Journals …

Synthesis of 1, 2, 3-triazoles by cycloadditions of azides with enol ethers

DR Roque, JL Neill, JW Antoon, EP Stevens - Synthesis, 2005 - thieme-connect.com
Triazoles were prepared in good to modest yields by cycloaddition of alkyl azides onto enol
ethers under solventless conditions. The reaction can access ring-fused triazoles that are …

Перспективные точки роста и вызовы фторорганической химии

ЛВ Политанская, ГА Селиванова, ЕВ Пантелеева… - Успехи химии, 2019 - mathnet.ru
В настоящее время химия фторорганических соединений является одной из
лидирующих и быстро прогрессирующих областей органической химии. Наличие в …

Quinine-catalyzed enantioselective desymmetrization of meso-aziridines with benzenethiols

Z Wang, X Sun, S Ye, W Wang, B Wang, J Wu - Tetrahedron: Asymmetry, 2008 - Elsevier
Ring opening of meso-aziridines with benzenethiols utilizing quinine as an organocatalyst
has been developed. The reaction proceeded smoothly in the presence of 10mol% of …

On the α-lithiation-rearrangement of N-toluensulfonyl aziridines: mechanistic and synthetic aspects

P O'Brien, CM Rosser, D Caine - Tetrahedron, 2003 - Elsevier
A detailed study of the rearrangement of five cycloalkene N-toluenesulfonyl (tosyl) aziridines
using sec-butyllithium (with and without added ligands such as (−)-sparteine and TMEDA) …