Hydrosilylation of aldehydes and ketones catalysed by bis (phosphinite) pincer platinum hydride complexes
J Chang, F Fang, J Zhang… - Advanced Synthesis & …, 2020 - Wiley Online Library
Bis (phosphinite) pincer platinum hydride complexes,[2, 6‐(R2PO) 2C6H3] PtH (R= tBu, iPr),
were synthesized, characterized and applied to the hydrosilylation of aldehydes and …
were synthesized, characterized and applied to the hydrosilylation of aldehydes and …
Preparation of Incomplete Cubane-Type Ru2M(μ3-S)(μ2-Cl)3 Clusters (M = Sb, Bi) and Isolation of the Ru2Sb Cluster Having a Novel μ3-SO Ligand. Functions in Oxygen Atom Transfer and Catalytic …
K Oya, H Seino, M Akiizumi, Y Mizobe - Organometallics, 2011 - ACS Publications
Cubane-type clusters containing Ru and group 15 metal [(Cp∧ RuCl) 2 (μ-SMCl2) 2](2a, M=
Bi; 2b, M= Sb; Cp∧= η5-C5EtMe4) reacted with O2 gas (1 atm) in 1, 2-dichloroethane (DCE) …
Bi; 2b, M= Sb; Cp∧= η5-C5EtMe4) reacted with O2 gas (1 atm) in 1, 2-dichloroethane (DCE) …
Binuclear Oxidative Addition of Sb–Cl Bonds: A Facile Synthetic Route to Main Group–Transition Element Clusters and Rings
YZ Li, R Ganguly, WK Leong - Organometallics, 2014 - ACS Publications
Binuclear oxidative addition of Sb–Cl bonds with the clusters Os3 (CO) 11 (NCCH3), 1, or
Os3 (CO) 10 (NCCH3) 2, 2, was found to be an effective synthetic route to organometallic …
Os3 (CO) 10 (NCCH3) 2, 2, was found to be an effective synthetic route to organometallic …
Reactions of Bis(tri-tert-butylphosphine)platinum with Metal Hydride Complexes. The Reactions of Pt(Pt-Bu3)2 with HRe(CO)4SbPh3
RD Adams, WC Pearl Jr - Organometallics, 2010 - ACS Publications
Pt (Pt-Bu3) 2 reacts with the rhenium hydride complex HRe (CO) 4 (SbPh3), 1, at 25° C to
give the complex PtRe (CO) 4 (Ph)(Pt-Bu3)(μ-SbPh2)(μ-H), 2, in 75% yield by the oxidative …
give the complex PtRe (CO) 4 (Ph)(Pt-Bu3)(μ-SbPh2)(μ-H), 2, in 75% yield by the oxidative …
Polynuclear ruthenium clusters containing stibine, stibene, and stibinidene ligands
The reaction of [Ru 3 (CO) 10 (µ-dppm)] with SbPh 3 has been investigated. Me 3 NO
activation of [Ru 3 (CO) 10 (µ-dppm)] in the presence of excess SbPh 3 yields the known …
activation of [Ru 3 (CO) 10 (µ-dppm)] in the presence of excess SbPh 3 yields the known …
Group 4 Metal–Metal Bonds
LH Gade - Molecular Metal‐Metal Bonds: Compounds …, 2015 - Wiley Online Library
For the group 4 metals metal‐metal bonding interaction for homonuclear di‐and polynuclear
complexes remains almost unknown in contrast to a limited, but nevertheless steadily …
complexes remains almost unknown in contrast to a limited, but nevertheless steadily …
Group 15 Metal–Metal Bonds
This chapter focuses solely on the metal‐metal bonded compounds containing
organometallic antimony or bismuth fragment. A review of the literature shows that metal …
organometallic antimony or bismuth fragment. A review of the literature shows that metal …
Synthesis and Reactivity of Ruthenium–Antimony Carbonyl Clusters
YZ Li, R Ganguly, WK Leong… - European Journal of …, 2015 - Wiley Online Library
Abstract The reaction of Na [HRu3 (CO) 11](2) with SbPh2Cl in dry tetrahydrofuran (THF)
afforded the cluster Ru3 (CO) 10 (μ‐H)(μ‐SbPh2)(3); in dry dichloromethane (DCM), the six …
afforded the cluster Ru3 (CO) 10 (μ‐H)(μ‐SbPh2)(3); in dry dichloromethane (DCM), the six …
Oxidative addition of halogen across an Os-Os or Os-Sb bond: formation of five-membered osmium-antimony carbonyl rings
YZ Li, R Ganguly, WK Leong - Journal of Organometallic Chemistry, 2016 - Elsevier
Halogenation of the cluster Os 3 (CO) 10 (μ-SbPh 2) 2, 2, with PhICl 2 or I 2 affords the five-
membered metallacyclic rings Os 3 (Cl) 2 (CO) 10 (μ-SbPh 2) 2, 3d and Os 3 (I) 2 (CO) 10 (μ …
membered metallacyclic rings Os 3 (Cl) 2 (CO) 10 (μ-SbPh 2) 2, 3d and Os 3 (I) 2 (CO) 10 (μ …
Trimetallic ReBiPt complexes containing spiro-bismuth ligands from the reaction of the bis (tri-t-butylphosphine) platinum with Re3 (CO) 12 (μ-BiPh2)(μ-H) 2
RD Adams, WC Pearl Jr - Journal of Organometallic Chemistry, 2011 - Elsevier
Pt (Pt-Bu3) 2 reacts with the bismuthtrirhenium complex Re3 (CO) 12 (μ-BiPh2)(μ-H) 2, 1 at
68° C to give eight complexes PtRe2 (CO) 9P (t-Bu3)(μ-H) 2, 2, PtRe3 (CO) 12P (t-Bu3)(μ …
68° C to give eight complexes PtRe2 (CO) 9P (t-Bu3)(μ-H) 2, 2, PtRe3 (CO) 12P (t-Bu3)(μ …