Organocobalt (III) complexes (R-CoIII), defined as cobalt complexes featuring a carbon–
cobalt bond, are largely used to produce carbon-centered radicals by homolytic cleavage of …

An extensive survey of the occurrences and origins of both structural trans-effects (STEs)
and kinetic trans-effects (KTEs) in octahedral d-transition metal complexes is presented. This …

Scientists in such fields as mathematics, physics, chemistry, biochemistry, biology, and
medicine are currently involved in investigations of porphyrins and their numerous …

We begin with a brief historical review of the development of our understanding of the
normal ordering of nd orbitals of a transition metal interacting with ligands, the most common …

Dieses Buch geht über die konventionelle Betrachtungsweise der Ergebnisse von
Strukturuntersuchungen weit hinaus: das mittlerweile verfügbare umfangreiche …

While free-radical chain reactions were known shortly after the turn of the 20th century, it
was not until the mid-1930s that free-radical polymerization was recognized. Today, free …

Lead (Pb)‐based perovskite solar cells (Pb‐PSCs) have been recorded with a fascinating
power conversion efficiency (PCE) of 25.5%. However, the presence of toxic Pb in the …

A simple one-step synthesis of [adenosylcobinamide]+ OH~(AdoCbi+ OH"), the base-free
derivative of adenosylcobalamin (AdoB12), is reported. The purity and identity of this product …

The inorganic chemistry of the cobalt corrinoids, derivatives of vitamin B 12, is reviewed, with
particular emphasis on equilibrium constants for, and kinetics of, their axial ligand …

Cobaloximes are promising, earth‐abundant catalysts for the light‐driven hydrogen
evolution reaction (HER). Typically, these cobalt (III) complexes are prepared in situ or …