Excited-state proton coupled charge transfer modulated by molecular structure and media polarization

AP Demchenko, KC Tang, PT Chou - Chemical Society Reviews, 2013 - pubs.rsc.org
Charge and proton transfer reactions in the excited states of organic dyes can be coupled in
many different ways. Despite the complementarity of charges, they can occur on different …

3-Hydroxyflavone derivatives: promising scaffolds for fluorescent imaging in cells

X Zhao, X Li, S Liang, X Dong, Z Zhang - RSC advances, 2021 - pubs.rsc.org
As a typical class of excited-state intramolecular proton transfer (ESIPT) molecules, 3-
hydroxyflavone derivatives (3HF, also known as flavonols) have received much attention …

Fluorescence turn on of coumarin derivatives by metal cations: a new signaling mechanism based on C= N isomerization

JS Wu, WM Liu, XQ Zhuang, F Wang, PF Wang… - Organic …, 2007 - ACS Publications
A new sensing mechanism based on CN isomerization, which shows a very significant
fluorescence enhancement to the metal cations in a simple and efficient way, is …

Multiparametric probing of intermolecular interactions with fluorescent dye exhibiting excited state intramolecular proton transfer

AS Klymchenko, AP Demchenko - Physical Chemistry Chemical …, 2003 - pubs.rsc.org
Excited-state intramolecular proton transfer (ESIPT) in 3-hydroxyflavone dyes allows us to
record, in addition to common spectroscopic parameters, the positions of absorption (νabs) …

Solvatochromic near-infrared probe for polarity mapping of biomembranes and lipid droplets in cells under stress

AH Ashoka, P Ashokkumar, YP Kovtun… - The Journal of …, 2019 - ACS Publications
Can polarity-sensitive fluorescent dyes monitor the response of live cells to fundamental
stress conditions, such as deprivation from nutrition and oxidative stress? To address this …

Electrochromic modulation of excited-state intramolecular proton transfer: the new principle in design of fluorescence sensors

AS Klymchenko, AP Demchenko - Journal of the American …, 2002 - ACS Publications
Internal Stark effect (or internal electrochromy) consists of the shift of light absorption and
emission bands under the influence of electric field produced by proximal charges. In the …

Modulation of the solvent-dependent dual emission in 3-hydroxychromones by substituents

AS Klymchenko, VG Pivovarenko, T Ozturk… - New journal of …, 2003 - pubs.rsc.org
3-Hydroxychromones (3HCs) are fluorescent dyes, which respond to solvent perturbations
by shifts and changes in the relative intensity of the two well-separated bands in the …

Toward Point-of-Care Detection of Mycobacterium tuberculosis: A Brighter Solvatochromic Probe Detects Mycobacteria within Minutes

M Kamariza, SGL Keyser, A Utz, BD Knapp, C Ealand… - JACS Au, 2021 - ACS Publications
There is an urgent need for point-of-care tuberculosis (TB) diagnostic methods that are fast,
inexpensive, and operationally simple. Here, we report on a bright solvatochromic dye …

Chromogenic and fluorogenic sensing of Cu2+ based on coumarin

A Helal, MHO Rashid, CH Choi, HS Kim - Tetrahedron, 2011 - Elsevier
A new highly selective, reversible, chromogenic, and fluorogenic chemosensor (4) based on
thiazole–coumarin moieties for quantification of copper ions in aqueous-DMSO was …

Novel two-band ratiometric fluorescence probes with different location and orientation in phospholipid membranes

AS Klymchenko, G Duportail, T Ozturk… - Chemistry & Biology, 2002 - cell.com
hydroxyflavone (3-HF) derivatives are very attractive fluorescence sensors due to their ability
to respond to small changes in their microenvironment via a dramatic alteration of the …