Polyoxometalates (POMs) represent an important group of metal–oxo nanoclusters, typically
comprised of early transition metals in high oxidation states (mainly V, Mo and W). Many …

Polyoxometalates (POMs), an exceptional family of coordination clusters consisting of Mo,
W, V, etc. early transition metal ions in their highest oxidation states, have received …

Polyoxometalate (POM) based supramolecular assemblies have received significant
attention over recent years because of their unique and diverse redox and photochemical …

The rational design and synthesis of organic–inorganic hybrids in molecular and material
sciences lies at the interface of several domains, such as synthetic organic and inorganic …

Abstract Wells-Dawson polyoxometalates (WD POMs) are an important subgroup within the
diverse family of POMs. In the last two decades, there has been remarkable progress in the …

Finding new ways of using visible light (or, more specifically, solar irradiation) to drive
commercially significant and/or challenging chemical processes is an ongoing research …

Sunlight and water are among the most plentiful and sustainable resources of energy.
Natural photosystem II in the plants uses these resources in ecofriendly manner for the …

Access to asymmetrically functionalized polyoxometalates is a grand challenge as it could
lead to new molecular nanomaterials with multiple or modular functionality. Now, a simple …

A new coordination polymer,(H2bpe)(Hbpe) 2 {[Cu (pzta)(H2O)][P2W18O62]}· 5H2O
(1)(pztaH= 5-(2-pyrazinyl) tetrazolate, bpe= bis (4-pyridyl) ethylene), was synthesized by the …

The visible‐light‐driven hydrogen evolution reaction (HER) by covalent photosensitizer–
catalyst dyads is one of the most elegant concepts in supramolecular homogeneous solar …