Click chemistry with cyclopentadiene
BJ Levandowski, RT Raines - Chemical reviews, 2021 - ACS Publications
Cyclopentadiene is one of the most reactive dienes in normal electron-demand Diels–Alder
reactions. The high reactivities and yields of cyclopentadiene cycloadditions make them …
reactions. The high reactivities and yields of cyclopentadiene cycloadditions make them …
Production and dynamic mechanical analysis of macro-scale functionalized polydicyclopentadiene Objects facilitated by rational synthesis and reaction injection …
Polydicyclopentadiene (PDCPD) is a ring-opening metathesis polymer derived from
dicyclopentadiene. Valued for its light weight, excellent material strength, and good …
dicyclopentadiene. Valued for its light weight, excellent material strength, and good …
Thermal rearrangement of optically active tetradeuterated 2-methoxymethyl-methylenecyclopropane and the bent bond/antiperiplanar hypothesis
G Deslongchamps, P Deslongchamps - Organic & Biomolecular …, 2019 - pubs.rsc.org
The thermolysis of an optically active tetradeuterated 2-methoxymethyl
methylenecyclopropane produces a specific ratio of eight possible rearrangement …
methylenecyclopropane produces a specific ratio of eight possible rearrangement …
The thermal rearrangements of naphthalene and azulene. An analysis through the bent bond and antiperiplanar hypothesis orbital model
P Deslongchamps - Tetrahedron, 2021 - Elsevier
The thermal conversion of azulene, naphthalene, norcaradiene, and polycyclic analogues
can be rationalized through the Bent Bond/Antiperiplanar Hypothesis (BBAH) orbital model …
can be rationalized through the Bent Bond/Antiperiplanar Hypothesis (BBAH) orbital model …
The conformation and reactivity of butadiene and the bent bond/antiperiplanar hypothesis orbital model
P Deslongchamps - Tetrahedron, 2021 - Elsevier
The bent bond/antiperiplanar hypothesis (BBAH) is a useful orbital model explaining the
conformational analysis and chemical reactivity of butadiene, the regioselective …
conformational analysis and chemical reactivity of butadiene, the regioselective …
Prying open a Thiele cage: discovery of an unprecedented extended pinacol rearrangement
Prying open a Thiele cage: discovery of an unprecedented extended pinacol rearrangement -
Chemical Communications (RSC Publishing) DOI:10.1039/C8CC08862D Royal Society of …
Chemical Communications (RSC Publishing) DOI:10.1039/C8CC08862D Royal Society of …
Bent bond/antiperiplanar hypothesis and antiaromatic, aromatic and nonaromatic molecules
P Deslongchamps - Tetrahedron, 2021 - Elsevier
The stereochemical reactivities of monocyclic unsaturated compounds having 3–5 and 7–8
membered rings and of bicyclic pentalenes and heptalene can be rationalized through the …
membered rings and of bicyclic pentalenes and heptalene can be rationalized through the …
Stereochemistry of Eʹ and Eʹʹ decarboxylative-dehydration reactions and the bent bond/antiperiplanar hypothesis orbital model
P Deslongchamps - Tetrahedron, 2021 - Elsevier
The known concerted decarboxylative-dehydration reaction of unsaturated hydroxy-
carboxylic acids 1–18 is analyzed through the Bent Bond/Antiperiplanar Hypothesis (BBAH) …
carboxylic acids 1–18 is analyzed through the Bent Bond/Antiperiplanar Hypothesis (BBAH) …
Revisiting the conformational analysis of unsaturated organic compounds using the bent bond/antiperiplanar hypothesis
G Deslongchamps, N Vatcher, P Deslongchamps - Tetrahedron, 2021 - Elsevier
The bent bond/antiperiplanar hypothesis (BBAH) offers a straightforward qualitative model
for interpreting the conformational analysis of simple unsaturated acyclic systems, as well as …
for interpreting the conformational analysis of simple unsaturated acyclic systems, as well as …
A new mechanism for the thermal and photochemical Diels-Alder cycloaddition based on the bent bond/antiperiplanar hypothesis orbital model
P Deslongchamps - Journal of Molecular Structure, 2022 - Elsevier
The thermal and photochemical stereochemical reactivity of norbornene derivatives (Diels-
Alder, retro-Diels-Alder, Cope rearrangement) can be rationalized through the Bent …
Alder, retro-Diels-Alder, Cope rearrangement) can be rationalized through the Bent …