Metal-catalyzed epoxidations of alkenes with hydrogen peroxide

BS Lane, K Burgess - Chemical reviews, 2003 - ACS Publications
Hydrogen peroxide is probably the best terminal oxidant after dioxygen with respect to
environmental and economic considerations. 1-4 Indeed, in certain circumstances, it is …

The Baeyer− Villiger reaction: New developments toward greener procedures

GJ Ten Brink, I Arends, RA Sheldon - Chemical Reviews, 2004 - ACS Publications
In 1899, Adolf Baeyer and Victor Villiger reported the oxidation of menthone to the
corresponding lactone (Figure 1) using a mixture of sodium persulfate and concentrated …

Recent developments on the epoxidation of alkenes using hydrogen peroxide as an oxidant

G Grigoropoulou, JH Clark, JA Elings - Green chemistry, 2003 - pubs.rsc.org
This paper reviews recent developments on the epoxidation of alkenes using hydrogen
peroxide as an environmentally friendly oxidant. The activation of hydrogen peroxide takes …

Recent advances in catalytic asymmetric epoxidation using the environmentally benign oxidant hydrogen peroxide and its derivatives

G De Faveri, G Ilyashenko, M Watkinson - Chemical Society Reviews, 2011 - pubs.rsc.org
There has been a recent drive to develop asymmetric catalytic methods to produce epoxides
using environmentally benign oxidants, especially hydrogen peroxide. This critical review …

Manganese-catalyzed epoxidations of alkenes in bicarbonate solutions

BS Lane, M Vogt, VJ DeRose… - Journal of the American …, 2002 - ACS Publications
This paper describes a method, discovered and refined by parallel screening, for the
epoxidation of alkenes. It uses hydrogen peroxide as the terminal oxidant, is promoted by …

Epoxidation of olefins with homogeneous catalysts–quo vadis?

SA Hauser, M Cokoja, FE Kühn - Catalysis Science & Technology, 2013 - pubs.rsc.org
The epoxidation of olefins catalyzed by molecular transition metal compounds is a research
field, which has been extensively studied over the past forty years. To date, numerous types …

Recent developments in selective catalytic epoxidations with H2O2

I Arends, RA Sheldon - Topics in Catalysis, 2002 - Springer
In this review the state-of-the-art of catalytic processes known today for selective
epoxidations using aqueous H 2 O 2 as the oxidant is presented. Recent achievements from …

Trace detection of hydrogen peroxide via dynamic double emulsions

D Fong, TM Swager - Journal of the American Chemical Society, 2021 - ACS Publications
Hydrogen peroxide is a dynamic signaling molecule in biological systems. We report herein
a versatile double emulsion sensor that can detect femtomolar quantities of aqueous …

Recent advances in oxidation catalysis using ionic liquids as solvents

D Betz, P Altmann, M Cokoja, WA Herrmann… - Coordination Chemistry …, 2011 - Elsevier
Ionic liquids are an interesting alternative to classical solvents presenting several
advantages. A variety of catalysts show good or even enhanced activities when applied in …

Molybdenum (VI) dioxo complexes employing Schiff base ligands with an intramolecular donor for highly selective olefin epoxidation

ME Judmaier, C Holzer, M Volpe… - Inorganic …, 2012 - ACS Publications
Reaction of [MoO2 (η2-t Bu2pz) 2] with Schiff base ligands HLX (X= 1–5) gave molybdenum
(VI) dioxo complexes of the type cis-[MoO2 (LX) 2] as yellow to light brown solids in …