Advances in reference materials and measurement techniques for greenhouse gas atmospheric observations

PJ Brewer, JS Kim, S Lee, OA Tarasova, J Viallon… - Metrologia, 2019 - iopscience.iop.org
We present the global research landscape which aims to deliver a measurement
infrastructure to underpin atmospheric observations of key greenhouse gases governing …

Towards traceability in CO2 line strength measurements by TDLAS at 2.7 µm

A Pogány, O Ott, O Werhahn, V Ebert - Journal of Quantitative Spectroscopy …, 2013 - Elsevier
Direct tunable diode laser absorption spectroscopy (TDLAS) was combined in this study with
metrological principles on the determination of uncertainties to measure the line strengths of …

Investigating adsorption/desorption of carbon dioxide in aluminum compressed gas cylinders

WR Miller Jr, GC Rhoderick, FR Guenther - Analytical chemistry, 2015 - ACS Publications
Between June 2010 and June 2011, the National Institute of Standards and Technology
(NIST) gravimetrically prepared a suite of 20 carbon dioxide (CO2) in air primary standard …

Development of a northern continental air standard reference material

GC Rhoderick, DR Kitzis, ME Kelley, WR Miller… - Analytical …, 2016 - ACS Publications
The National Institute of Standards and Technology (NIST) recently began to develop
standard mixtures of greenhouse gases as part of a broad program mandated by the 2009 …

SI traceability and scales for underpinning atmospheric monitoring of greenhouse gases

PJ Brewer, RJC Brown, OA Tarasova, B Hall… - Metrologia, 2018 - iopscience.iop.org
Metrological traceability is the property of a measurement result whereby it can be related to
a stated reference through a documented unbroken chain of calibrations, each contributing …

[HTML][HTML] Generation of CO2 gas mixtures by dynamic dilution for the development of gaseous certified reference materials

F Rolle, F Durbiano, FR Pennecchi, S Pavarelli… - Measurement …, 2022 - Elsevier
Abstract The use of Certified Reference Materials (CRMs) is of utmost importance to achieve
the comparability and traceability of data, which are essential features of measurement …

Carbon dioxide determination in atmosphere by non dispersive infrared spectroscopy: A possible approach towards the comparability with seawater CO2 …

F Rolle, M Sega - Measurement, 2018 - Elsevier
The rising levels of carbon dioxide in the atmosphere are responsible for fundamental
changes occurring in seawater carbonate chemistry. The partial pressure of oceanic CO 2 …

An FTIR method for accurate CO2 mole fraction measurements with correction for differences in isotopic composition of gases

E Flores, J Viallon, P Moussay, F Idrees… - Metrologia, 2019 - iopscience.iop.org
The precision of optically based techniques for long term CO 2 monitoring in the atmosphere
is approaching the±0.02 µmol mol− 1 level, however biases of potentially up to fifteen times …

High-precision analysis of SF6 at ambient level

JS Lim, DM Moon, JS Kim, WT Yun… - Atmospheric …, 2013 - amt.copernicus.org
This work reports on the development of a technique for the precise analysis of ambient SF
6. This technique, which involves a gas chromatograph/electron capture detector (GC-ECD) …

Breakthrough in negating the impact of adsorption in gas reference materials

PJ Brewer, RJC Brown, EB Mussell Webber… - Analytical …, 2019 - ACS Publications
We have shown that an exchange dilution preparation method reduces the impact of surface
adsorption of the target component in high-pressure gas mixtures used for underpinning …