For almost 40 years, difluoromethylene phosphonates have proven to be versatile molecular
tools in biochemical studies owing to their close resemblance to naturally occurring …

The chemistry of hypervalent iodine reagents has now become quite valuable due to the
reactivity of these compounds under mild reaction conditions and their resemblance in …

Dess-Martin periodinane (DMP) is one of the hypervalent iodines that is most frequently
utilized as an oxidizing agent in organic chemistry. The authors of this septennial review …

Polyfluoroarenes have been known for a long time, but they are most often used as
fluorinated building blocks for the synthesis of aromatic compounds. At the same time, due to …

The first enantioselective phosphonyldifluoromethylation is enabled by the use of diethyl
(difluoro (trimethylsilyl)-methyl) phosphonate reagent as a latent pronucleophile in the Lewis …

Described is a physical organic study of the reduction of three sets of carbonyl compounds
by the NADPH-dependent enzyme Clostridium acetobutylicum alcohol dehydrogenase …

Mixed phosphonates attract much attention in medicinal chemistry for drugs discovery. We
report herein the alkylation of a phosphonamidate to access to functionalized …

Dess-Martin periodinane has been demonstrated for the first time to be an efficient reagent
in metal–free oxidation of α-hydroxyphosphonates to α-ketophosphonates under ambient …

The synthesis of β-hydroxy-α, α-difluorosulfonamides was achieved by reacting
difluoromethanesulfonamides with KHMDS in the presence of an aldehyde or ketone. The …

We describe a method for the preparation of CF 2-P (V) building blocks and monomers for
biological and materials chemistry applications in multigram quantities based on a formal [2 …