Water at charged interfaces
The ubiquity of aqueous solutions in contact with charged surfaces and the realization that
the molecular-level details of water–surface interactions often determine interfacial functions …
the molecular-level details of water–surface interactions often determine interfacial functions …
Multiscale modeling of aqueous electric double layers
From the stability of colloidal suspensions to the charging of electrodes, electric double
layers play a pivotal role in aqueous systems. The interactions between interfaces, water …
layers play a pivotal role in aqueous systems. The interactions between interfaces, water …
How cations affect the electric double layer and the rates and selectivity of electrocatalytic processes
Electrocatalysis is central to the production of renewable fuels and high-value commodity
chemicals. The electrolyte and the electrode together determine the catalytic properties of …
chemicals. The electrolyte and the electrode together determine the catalytic properties of …
Determination of surface potential and electrical double-layer structure at the aqueous electrolyte-nanoparticle interface
The structure of the electrical double layer has been debated for well over a century, since it
mediates colloidal interactions, regulates surface structure, controls reactivity, sets …
mediates colloidal interactions, regulates surface structure, controls reactivity, sets …
Probing liquid/solid interfaces at the molecular level
F Zaera - Chemical reviews, 2012 - ACS Publications
The ability to obtain a molecular-level understanding of the chemistry that takes place at
liquid/solid interfaces is key to the development and improvement of many chemical and …
liquid/solid interfaces is key to the development and improvement of many chemical and …
Nature of cations critically affects water at the negatively charged silica interface
Understanding the collective behavior of ions at charged surfaces is of paramount
importance for geological and electrochemical processes. Ions screen the surface charge …
importance for geological and electrochemical processes. Ions screen the surface charge …
Specific ion effects on particle aggregation induced by monovalent salts within the Hofmeister series
Ion specific effects of monovalent salts on charging and aggregation for two types of
polystyrene latex particles were investigated by electrophoresis and time-resolved light …
polystyrene latex particles were investigated by electrophoresis and time-resolved light …
Liquid flow along a solid surface reversibly alters interfacial chemistry
In nature, aqueous solutions often move collectively along solid surfaces (for example,
raindrops falling on the ground and rivers flowing through riverbeds). However, the influence …
raindrops falling on the ground and rivers flowing through riverbeds). However, the influence …
Role of ions on the surface-bound water structure at the silica/water interface: Identifying the spectral signature of stability
Isolating the hydrogen-bonding structure of water immediately at the surface is challenging,
even with surface-specific techniques like sum-frequency generation (SFG), because of the …
even with surface-specific techniques like sum-frequency generation (SFG), because of the …
The effect of salt on the water structure at a charged solid surface: differentiating second-and third-order nonlinear contributions
We have used visible-infrared sum-frequency generation spectroscopy to reveal
fundamental characteristics of water structure at the fused silica surface. By studying a wide …
fundamental characteristics of water structure at the fused silica surface. By studying a wide …