Applications of halogen-atom transfer (XAT) for the generation of carbon radicals in synthetic photochemistry and photocatalysis
The halogen-atom transfer (XAT) is one of the most important and applied processes for the
generation of carbon radicals in synthetic chemistry. In this review, we summarize and …
generation of carbon radicals in synthetic chemistry. In this review, we summarize and …
Precision polymer synthesis by controlled radical polymerization: Fusing the progress from polymer chemistry and reaction engineering
During the first 100 years of polymer science, controlled radical polymerization (also
recommended as reversible deactivation radical polymerization) is undoubtedly a …
recommended as reversible deactivation radical polymerization) is undoubtedly a …
[HTML][HTML] Copper-mediated living radical polymerization (atom transfer radical polymerization and copper (0) mediated polymerization): from fundamentals to …
The discovery of the first “living” radical polymerization by Otsu and co-workers (1) in 1982
heralded the start of a very exciting time for polymer chemists. Since then, a plethora of living …
heralded the start of a very exciting time for polymer chemists. Since then, a plethora of living …
Nitroxide-mediated polymerization
Nitroxide-mediated polymerization (NMP) is a controlled/living radical polymerization
(CLRP) technique that enables the design of well-defined, functional and complex …
(CLRP) technique that enables the design of well-defined, functional and complex …
Brush-modified materials: Control of molecular architecture, assembly behavior, properties and applications
Recent progress in surface-initiated polymerization enables the deliberate polymer
modification of nanoscopic surfaces with high levels of precision. This has given rise to the …
modification of nanoscopic surfaces with high levels of precision. This has given rise to the …
Photoinitiated polymerization: advances, challenges, and opportunities
Y Yagci, S Jockusch, NJ Turro - Macromolecules, 2010 - ACS Publications
The use of photoinitiated polymerization is continuously growing in industry as reflected by
the large number of applications in not only conventional areas such as coatings, inks, and …
the large number of applications in not only conventional areas such as coatings, inks, and …
New polymer synthesis by nitroxide mediated living radical polymerizations
At first glance, radical polymerization may be considered a mature technology with millions
of tons of vinyl based homo-and copolymers being produced annually. This perception of …
of tons of vinyl based homo-and copolymers being produced annually. This perception of …
Living radical polymerization by the RAFT process
This paper presents a review of living radical polymerization achieved with thiocarbonylthio
compounds [ZC (= S) SR] by a mechanism of reversible addition–fragmentation chain …
compounds [ZC (= S) SR] by a mechanism of reversible addition–fragmentation chain …
The persistent radical effect: a principle for selective radical reactions and living radical polymerizations
H Fischer - Chemical reviews, 2001 - ACS Publications
From time to time reactions involving both transient and persistent radical intermediates
were discovered that lead to a highly dominant and unusually selective formation of the …
were discovered that lead to a highly dominant and unusually selective formation of the …
[图书][B] Oxidation and antioxidants in organic chemistry and biology
ET Denisov, IB Afanas' ev - 2005 - taylorfrancis.com
Providing a comprehensive review of reactions of oxidation for different classes of organic
compounds and polymers, and biological processes mediated by free radicals, Oxidation …
compounds and polymers, and biological processes mediated by free radicals, Oxidation …