Nonbiaryl and heterobiaryl atropisomers: molecular templates with promise for atropselective chemical transformations

E Kumarasamy, R Raghunathan, MP Sibi… - Chemical …, 2015 - ACS Publications
Chirality plays a crucial role in life-sustaining processes, and for this reason asymmetric
synthesis has been a central research theme in many research groups in the field of organic …

Supramolecular photochemistry as a potential synthetic tool: photocycloaddition

V Ramamurthy, J Sivaguru - Chemical reviews, 2016 - ACS Publications
Photochemistry, bearing significant applications in natural and man-made events such as
photosynthesis, vision, photolithography, photodynamic therapy, etc., is yet to become a …

The Paternò–Büchi reaction–a comprehensive review

M D'Auria - Photochemical & Photobiological Sciences, 2019 - pubs.rsc.org
The photochemical reaction between an excited state of carbonyl compounds and an alkene
to give the oxetane deriving from a cycloaddition reaction (the Paternò–Büchi reaction) is …

[HTML][HTML] The Paternò-Büchi reaction—Mechanisms and application to organic synthesis

M Freneau, N Hoffmann - Journal of Photochemistry and Photobiology C …, 2017 - Elsevier
Abstract The [2+ 2] photocycloaddition between an electronically excited carbonyl
compound and an alkene leading to oxetanes (Paternò-Büchi reaction) is one of the most …

Tailoring Atropisomeric Maleimides for Stereospecific [2+ 2] Photocycloaddition Photochemical and Photophysical Investigations Leading to Visible-Light …

E Kumarasamy, R Raghunathan… - Journal of the …, 2014 - ACS Publications
Atropisomeric maleimides were synthesized and employed for stereospecific [2+ 2]
photocycloaddition. Efficient reaction was observed under direct irradiation, triplet-sensitized …

Visible light-induced difunctionalization of alkynes: the synthesis of thiazoles and 1, 1-dibromo-1-en-3-ynes

X Huang, H Chen, Z Huang, Y Xu, F Li… - The Journal of …, 2019 - ACS Publications
A visible light-induced cascade cyclization of thioamides with alkynes was developed to
synthesize 1, 3-thiozoles. The sulfur radical generated from thioamide via the single-electron …

Transposed Paternò–Büchi Reaction

E Kumarasamy, R Raghunathan… - Journal of the …, 2017 - ACS Publications
A complementary strategy of utilizing ππ* excited state of alkene instead of nπ* excited state
of the carbonyl chromophore in a “transposed Paternò–Büchi” reaction is evaluated with …

Synthesis and evaluation of terpolymers consist of methacrylates with maleic anhydride and methacrylic morpholine and their amine compound as pour point …

M Zhou, Y He, Y Chen, Y Yang, H Lin, S Han - Energy & Fuels, 2015 - ACS Publications
Long-chain alkyl (ie, tetradecyl, hexadecyl, and octodecyl) methacrylate (MC), maleic
anhydride (MA), and methylamidemorpholine (MCNR2) were used in this study to prepare a …

Chirality Transfer Intramolecular Pauson–Khand Reaction with N–C Axially Chiral Sulfonamides Bearing an Ene–Yne Structure

R Kasahara, T Toyoda, S Fukasawa, A Takeuchi… - Organic …, 2023 - ACS Publications
An intramolecular Pauson–Khand reaction with enantioenriched N–C axially chiral N-allyl-N-
(2-alkynylphenyl) sulfonamide derivatives proceeded with complete chirality transfer from …

Tale of twisted molecules. Atropselective photoreactions: taming light induced asymmetric transformations through non-biaryl atropisomers

E Kumarasamy, AJL Ayitou, N Vallavoju… - Accounts of Chemical …, 2016 - ACS Publications
Conspectus Photochemical transformations are a powerful tool in organic synthesis to
access structurally complex and diverse synthetic building blocks. However, this great …