The unimolecular chemistry of methyl chloroformate ions and neutrals: A story of near-threshold decomposition

B Lowe, AL Cardona, A Bodi, PM Mayer… - Journal of the …, 2023 - ACS Publications
The near-threshold dissociation of ionized and neutral methyl chloroformate (CH3COOCl,
MCF) was explored with imaging photoelectron photoion coincidence spectroscopy. The …

High-resolution double velocity map imaging photoelectron photoion coincidence spectrometer for gas-phase reaction kinetics

D Rosch, R Almeida, B Sztáray… - The Journal of Physical …, 2022 - ACS Publications
We present a new photoelectron photoion coincidence (PEPICO) spectrometer that
combines high mass resolution of cations with independently adjustable velocity map …

A vacuum ultraviolet photoionization time‐of‐flight mass spectrometer with high sensitivity for study of gas‐phase radical reaction in a flow tube

Z Wen, X Tang, C Wang, C Fittschen… - … Journal of Chemical …, 2019 - Wiley Online Library
Photoionization mass spectrometry as a powerful analytical method has been widely utilized
and provided valuable insight in the field of gas‐phase reactions. Here, a highly sensitive …

Probing the pyrolysis of methyl formate in the dilute gas phase by synchrotron radiation and theory

B Lowe, AL Cardona, J Salas, A Bodi… - Journal of Mass …, 2022 - Wiley Online Library
The thermal dissociation of the atmospheric constituent methyl formate was probed by
coupling pyrolysis with imaging photoelectron photoion coincidence spectroscopy …

Probing the pyrolysis of ethyl formate in the dilute gas phase by synchrotron radiation and theory

B Lowe, AL Cardona, J Salas, A Bodi… - Journal of Mass …, 2023 - Wiley Online Library
The thermal decomposition of the atmospheric constituent ethyl formate was studied by
coupling flash pyrolysis with imaging photoelectron photoion coincidence (iPEPICO) …

Dissociation of State-Selected Ions Studied by Fixed-Photon-Energy Double-Imaging Photoelectron Photoion Coincidence: Cases of O2+ and CH3F+

X Tang, GA Garcia, L Nahon - Physchem, 2022 - mdpi.com
This study presents the method of fixed-photon-energy double-imaging photoelectron
photoion coincidence (i2PEPICO) utilized to investigate the dissociation of state-selected …

A vacuum ultraviolet photoionization time-of-flight mass spectrometer for investigation of free radical reaction

W Tao, T Xiao-Feng, W Zuo-Ying, CH Zhang… - Chinese Journal of …, 2020 - Elsevier
A home-made vacuum ultraviolet (VUV) photoionization linear time-of-flight mass
spectrometer (VUVPI-LTOFMS) was utilized to study atmospheric radical reactions. A …

Probing the Pyrolysis and Ion Chemistry of a Selection of Formates and Chloroformates

B Lowe - 2023 - ruor.uottawa.ca
This research explores the ion chemistry and pyrolysis of a selection of formates. Alternative
fuels have become increasingly popular over the past decade, one of particular interest is …