Helical self-assembled coordination complexes are broadly classified under linear and
circular helicates. While the number of strands of the ligand units in a molecule of the linear …

Helicity is an archetypal structural motif of many biological systems and provides a basis for
molecular recognition in DNA. Whilst artificial supramolecular hosts are often helical, the …

Chiral information transfer is crucial to design new functions like, for instance, sensing
through chiroptical probes in which the input is readout as a consequence of a chiral …

A combination of self‐complementary hydrogen bonding and metal–ligand interactions
allows stereocontrol in the self‐assembly of prochiral ligand scaffolds. A unique, non …

The self-assembly of three rheniumtricarbonyl core-based supramolecular coordination
complexes (SCCs), fac-[Re (CO) 3 (μ-L)(μ-L′) Re (CO) 3](1–3) was carried out using Re2 …

The ligands L1 and L2 both form separable dinuclear double‐stranded helicate and
mesocate complexes with RuII. In contrast to clinically approved platinates, the helicate …

A new class of double stranded dinuclear monohelicates, fac-[{Re (CO) 3-(μ-L)-Re (CO) 3}
Ln](1–4), were self-assembled from Re2 (CO) 10, a rigid bischelating donor (H2-L: 1, 4 …

In this work, a series of poly-NHC-based tetranuclear silver helicates and mesocates were
synthesized from the silver-mediated self-assembly of the ligands involving multiple …

The study of the inherent factors that influence the isolation of one type of
metallosupramolecular architecture over another is one of the main objectives in the field of …

A novel linear hybrid tris-bidentate neutral ligand having 2, 2′-bipyridine and two terminal
triazolylpyridine coordination sites (L) was efficiently synthesized and explored in the …