Carbenes: Synthesis, properties, and organometallic chemistry
P De Fremont, N Marion, SP Nolan - Coordination Chemistry Reviews, 2009 - Elsevier
Carbenes, thought of only as transient species for a long time, have become ubiquitous in
organometallic chemistry. Their interaction with a metal center, which allows for their …
organometallic chemistry. Their interaction with a metal center, which allows for their …
Synthetic approaches toward molecular and polymeric carbon allotropes
F Diederich, Y Rubin - Angewandte Chemie International …, 1992 - Wiley Online Library
Life on earth is based on compounds that have carbon frames and backbones. Today,
chemists have added to the world of biomolecules and biopolymers approximately 107 …
chemists have added to the world of biomolecules and biopolymers approximately 107 …
Silasesquioxanes as ligands in inorganic and organometallic chemistry
FJ Feher, TA Budzichowski - Polyhedron, 1995 - Elsevier
Silasesquioxanes are an interesting class of ligands for both main group and transition-
metal elements. A variety of coordination environments can be supported by …
metal elements. A variety of coordination environments can be supported by …
Silicon-mediated selective homo-and heterocoupling of carbon monoxide
While the transformation of carbon monoxide to multicarbon compounds (fuels and organic
bulk chemicals) via reductive scission of the enormously strong CO bond is dominated by …
bulk chemicals) via reductive scission of the enormously strong CO bond is dominated by …
Transition metal complexes containing all-carbon ligands
While small carbon molecules have been found in locations as diverse as interstellar
molecular clouds, carbon stars, hydrocarbon flames and laserablated carbon, bulk …
molecular clouds, carbon stars, hydrocarbon flames and laserablated carbon, bulk …
Oxidation Chemistry of Metal-Bonded C4 Chains: A Combined Chemical, Spectroelectrochemical, and Computational Study
The known complex {Cp (PPh3) 2Ru} 2 (μ-C⋮ CC⋮ C)(3-Ph) and its PMe3-substitution
product {Cp (PPh3)(PMe3) Ru} 2 (μ-C⋮ CC⋮ C)(3-Me) have been shown by cyclic …
product {Cp (PPh3)(PMe3) Ru} 2 (μ-C⋮ CC⋮ C)(3-Me) have been shown by cyclic …
Electronically unsaturated three-coordinate chloride and methyl complexes of iron, cobalt, and nickel
PL Holland, TR Cundari, LL Perez… - Journal of the …, 2002 - ACS Publications
Three-coordinate organometallic complexes are rare, especially with the prototypical methyl
ligand. Using a hindered, rigid bidentate ligand (L), it is possible to create 12-electron …
ligand. Using a hindered, rigid bidentate ligand (L), it is possible to create 12-electron …
Tri-tert-butylsilyl) imido complexes of titanium: benzene carbon-hydrogen activation and structure of [(tert-Bu3SiNH) Ti] 2 (. mu.-NSi-tert-Bu3) 2
CC Cummins, CP Schaller… - Journal of the …, 1991 - ACS Publications
Treatmentof TiCl4 (THF) 2 with 3.0 equiv of'Bu3SiNHLi in Et20 produced (* Bu3SiNH) 3TiCl
(1; 82%). An attempt to alkylate 1 with MeMgBr led to (lBu3SiNH) 3TiBr (2), alternatively …
(1; 82%). An attempt to alkylate 1 with MeMgBr led to (lBu3SiNH) 3TiBr (2), alternatively …
Phosphinidenetantalum(V) Complexes of the Type [(N3N)TaPR] as Phospha‐Wittig Reagents
CC Cummins, RR Schrock… - … International Edition in …, 1993 - Wiley Online Library
2.27 (SiMi3) 194.73 (d,'Jpc= 48.3, P= c7 38.05 kl. 2Jw= 12.2. CCMEd 32.16 (a I&= 34.2.
pcMdj 31.03 (Q 3fpc= 12.9, W q) 30.42 (4 2Jpc= 11.5. PCMeJ) 200.85 (4 1Jpc= 40.8, P= C) …
pcMdj 31.03 (Q 3fpc= 12.9, W q) 30.42 (4 2Jpc= 11.5. PCMeJ) 200.85 (4 1Jpc= 40.8, P= C) …
Chemistry of electrophilic metal centres coordinated by silox (tBu3SiO), tritox (tBu3CO) and related binfunctional ligands
PT Wolczanski - Polyhedron, 1995 - Elsevier
Bulky siloxide and alkoxide ligands, notably silox (tBu3SiO), and tritox (tBu3CO), have been
employed as ancillary ligands in the chemistry of low-coordinate early transition metal …
employed as ancillary ligands in the chemistry of low-coordinate early transition metal …