Abstract (Hetero) arenes continue to prove their indispensability in pharmaceuticals,
materials science, and synthetic chemistry. As such, the controllable modification of …

Seven membered heterocyclic Azepine and its derivatives have great pharmacological and
therapeutic implications. In this review, the literature of the last fifty years has been exploited …

Tetrahydrobenzo [b] azepines (THBAs) are commonly found in many bioactive compounds;
however, the modular preparation of functionalized THBAs remains challenging to date …

A novel platform for the skeletal editing of single C–C bonds via a single-carbon insertion
has been developed using diazirines. This strategy involves the photogeneration of …

Herein, we report the preparation of bridged tetrahydrobenzo [b] azepines, which was
accomplished through an aza‐Piancatelli cyclization/Michael addition sequence in a one …

Natural products are well established as an important resource and play an important role in
drug discovery. Here, two pyrrolinone-fused benzoazepine alkaloids,(+)-asperazepanones …

Herein, we report a unified approach to azepines by dearomative photochemical
rearrangement of aromatic N-ylides. Deprotonation of quaternary aromatic salts with 1, 8 …

A catalyst-free [4+ 3]-cycloaddition reaction of N-aryl sulfilimines with cyclobutenones is
described, which provides a straightforward protocol for synthesizing 1, 5-dihydro-2 H-benzo …

Quinoline derivatives are frequently found in natural products and biologically active
compounds; however, construction of quinoline fused polyheterocycles is a challenging goal …

The Pd (II)-catalyzed cascade reactions of 2-(cyanomethoxy) chalcones with arylboronic
acids were demonstrated, allowing the rapid construction of benzofuro [2, 3-c] pyridine …