Diamines are synthetically important motifs in organo‐catalysis, natural products, and drug
research. Continuous utilization of transition‐metal based catalyst in direct 1, 2‐diamination …

Intermolecular carboselenenylation of easily accessible alkenes by utilizing diselenides and
N-fluorobenzenesulfonimide (NFSI) under metal-free and mild conditions is reported …

A cobalt-catalyzed aminofluorination reaction of styrenes with N-fluorosulfonamides serving
as both the amination and fluorination agents has been developed. The switch of selectivity …

Catalytic hydroamination of the readily available alkenes is among the most straightforward
means to construct diverse alkyl amines. To this end, the facile access to both …

Catalytic imidation using NFSI as the nitrogen source has become an emerging tool for
oxidative carbon–nitrogen bond formation. However, the less than ideal …

Abstract The AuI complex [Au {N (F) SO2Ph}(SPhos)](SPhos= dicyclohexyl (2′, 6′‐
dimethoxy [1, 1′‐biphenyl]‐2‐yl) phosphane)(2) bearing a fluoroamido ligand has been …

In the search for versatile reagents compatible with mechanochemical techniques, in this
work we studied the reactivity of N-fluorobenzenesulfonimide (NFSI) by ball milling. We …

Activated by multiple consecutive oxidative radical‐polar crossover and desaturation
processes, the selective diamination of arylcyclobutanes, which is difficult to perform by …

CuAAC and SuFEx reactions are two major tools to connect molecules in click chemistry. An
azide plays the pivotal role in the former, and a fluorosulfonyl group is the key functionality in …

The palladium-catalyzed aminofluorination of styrenes using novel N-
fluorobenzenesulfonimide (NFSI) derivatives with deprotectable substituents, and the …