Molecular polaritonics: Chemical dynamics under strong light–matter coupling

TE Li, B Cui, JE Subotnik, A Nitzan - Annual review of physical …, 2022 - annualreviews.org
Chemical manifestations of strong light–matter coupling have recently been a subject of
intense experimental and theoretical studies. Here we review the present status of this field …

Expanded theory of H-and J-molecular aggregates: the effects of vibronic coupling and intermolecular charge transfer

NJ Hestand, FC Spano - Chemical reviews, 2018 - ACS Publications
The electronic excited states of molecular aggregates and their photophysical signatures
have long fascinated spectroscopists and theoreticians alike since the advent of Frenkel …

Polariton chemistry: controlling molecular dynamics with optical cavities

RF Ribeiro, LA Martínez-Martínez, M Du… - Chemical …, 2018 - pubs.rsc.org
Molecular polaritons are the optical excitations which emerge when molecular transitions
interact strongly with confined electromagnetic fields. Increasing interest in the hybrid …

Molecular polaritons for controlling chemistry with quantum optics

F Herrera, J Owrutsky - The Journal of chemical physics, 2020 - pubs.aip.org
This is a tutorial-style introduction to the field of molecular polaritons. We describe the basic
physical principles and consequences of strong light–matter coupling common to molecular …

Introduction to the Dicke Model: From Equilibrium to Nonequilibrium, and Vice Versa

P Kirton, MM Roses, J Keeling… - Advanced Quantum …, 2019 - Wiley Online Library
The Dicke model describes the coupling between a quantized cavity field and a large
ensemble of two‐level atoms. When the number of atoms tends to infinity, this model can …

Strong light-matter coupling in quantum chemistry and quantum photonics

J Flick, N Rivera, P Narang - Nanophotonics, 2018 - degruyter.com
In this article, we review strong light-matter coupling at the interface of materials science,
quantum chemistry, and quantum photonics. The control of light and heat at thermodynamic …

Simulating molecular polaritons in the collective regime using few-molecule models

JB Pérez-Sánchez, A Koner… - Proceedings of the …, 2023 - National Acad Sciences
The study of molecular polaritons beyond simple quantum emitter ensemble models (eg,
Tavis–Cummings) is challenging due to the large dimensionality of these systems and the …

Relevance of the quadratic diamagnetic and self-polarization terms in cavity quantum electrodynamics

C Schäfer, M Ruggenthaler, V Rokaj, A Rubio - ACS photonics, 2020 - ACS Publications
Experiments at the interface of quantum optics and chemistry have revealed that strong
coupling between light and matter can substantially modify the chemical and physical …

Cavity Casimir-Polder forces and their effects in ground-state chemical reactivity

J Galego, C Climent, FJ Garcia-Vidal, J Feist - Physical Review X, 2019 - APS
Here, we present a fundamental study on how the ground-state chemical reactivity of a
single molecule can be modified in a QED scenario, ie, when it is placed inside a nanoscale …

Open quantum systems with local and collective incoherent processes: Efficient numerical simulations using permutational invariance

N Shammah, S Ahmed, N Lambert, S De Liberato… - Physical Review A, 2018 - APS
The permutational invariance of identical two-level systems allows for an exponential
reduction in the computational resources required to study the Lindblad dynamics of …