Although experimental methods can be used to obtain the quantitative kinetics of
atmospheric reactions, experimental data are often limited to a narrow temperature range …

Differences in entropies of competing transition states can direct kinetic selectivity.
Understanding and modeling such entropy differences at the molecular level is complicated …

A priori rate predictions for gas phase reactions have undergone a gradual but dramatic
transformation, with current predictions often rivaling the accuracy of the best available …

Kinetics provides the fundamental parameters for elucidating sources and sinks of key
atmospheric species and for atmospheric modeling more generally. Obtaining quantitative …

Criegee intermediates in the atmosphere serve as oxidizing agents to initiate aerosol
formation, which are particularly important for atmospheric modeling, and understanding …

A special type of C–H functionalization can be achieved through C–H insertion combined
with Cope rearrangement (CHCR) in the presence of dirhodium catalysts. This type of …

Kinetics measurements on radical–radical reactions are often unavailable experimentally,
and obtaining quantitative rate constants for such reactions by theoretical methods is …

The kinetics of the reactions H 2 NO+ O 2 (3 Σ g−)→ HNO (X˜ 1 A′)+ HO 2 and NH 2+ HO
2→ NH 3+ O 2 (3 Σ g−), which are, respectively, very sensitive chain-propagation and chain …

Quantum mechanical tunneling (QMT) can play an important role in light element-related
chemical reactions; however, its influence on racemization is not fully understood. Herein …

Organic peroxy radicals (RO2) are key intermediates in the chemistry of the atmosphere.
One of the main sink reactions of RO2 is the recombination reaction RO2+ R′ O2, which …