The merger of photoredox catalysis with transition metal catalysis, termed
metallaphotoredox catalysis, has become a mainstay in synthetic methodology over the past …

Benefiting from the impressive increase in fundamental knowledge, the last 20 years have
shown a continuous burst of new ideas and consequently a plethora of new catalytic …

Redox processes are at the heart of synthetic methods that rely on either electrochemistry or
photoredox catalysis, but how do electrochemistry and photoredox catalysis compare? Both …

Photoredox chemistry with organic or transition metal agents has been reviewed in earlier
years, but such is the pace of progress that we will overlap very little with earlier …

We present here a review of the photochemical and electrochemical applications of multi-
site proton-coupled electron transfer (MS-PCET) in organic synthesis. MS-PCETs are redox …

Mechanistic investigations of the Ni-catalyzed asymmetric reductive alkenylation of N-
hydroxyphthalimide (NHP) esters and benzylic chlorides are reported. Investigations of the …

Conspectus The study of carbohydrates has emerged as a crucial research area in various
disciplines due to their pivotal roles in cellular processes. To facilitate in-depth exploration of …

Alcohols are commercially abundant and structurally diverse reservoirs of sp3-hybridized
chemical space. However, the direct utilization of alcohols in C–C bond-forming cross …

1, 2-Dicarbofunctionalization of alkenes has emerged as an efficient synthetic strategy for
preparing substituted molecules by coupling readily available alkenes with electrophiles …

Nickel-catalyzed reductive cross-coupling reactions have emerged as powerful methods to
join two electrophiles. These reactions have proven particularly useful for the coupling of sec …