Although radicals are usually viewed as neutral, relatively nonpolar species, polar effects in
radical chemistry are wellknown 1 and continue to be exploited in organic synthesis. 2 For …

Synthesis of heterocycles by radical cyclisation - Journal of the Chemical Society, Perkin
Transactions 1 (RSC Publishing) DOI:10.1039/B108582B Royal Society of Chemistry View PDF …

The abundance, structural diversity, and versatility of ketones give prominence to this
carbonyl functional group in synthetic chemistry. The assembly of ketones via the …

A simple and efficient procedure for the synthesis of a new class of selenoesters 4a and 4b
was developed. Polarized-light optical microscopy (POM), differential scanning calorimetry …

Time to change the light bulb: An alkyl dithiocarbamate, itself formed through a
photoinitiated group-transfer cyclization of a carbamoyl radical, undergoes a second …

A new radical‐based coupling method has been developed for the single‐step generation of
various γ‐amino acids and α, β‐diamino acids from α‐aminoacyl tellurides. Upon activation …

The application of acyl radicals in radical addition reactions in the absence of a CO
atmosphere is generally limited to aryl or α-unsubstituted alkyl acyl radicals due to …

Herein we report that ene reductases (EREDs) can facilitate an unprecedented
intramolecular β‐C− H functionalization reaction for the synthesis of bridged bicyclic …

An Fe (III)-catalyzed efficient method has been developed for the synthesis of selenoester
derivatives in high yields through the coupling of α-amino carbonyl/glycine derivatives and …

A variety of functionalised biaryls and heterobiaryls are prepared by intramolecular free
radical [1, 5]-ipso-substitution using sulfonamide and sulfonate derived tethering chains. The …