Electrochemistry, which employs electrons as reagents and avoids the use of traditional
redox reagents, becomes a powerful tool in oxidative dehydrogenation cross-coupling …

Transition metal catalysis is of utmost importance for the development of sustainable
processes in academia and industry. The activity and selectivity of metal complexes are …

Aliphatic allylic amines are found in a great variety of complex and biorelevant molecules.
The direct allylic C–H amination of alkenes serves as the most straightforward method …

A visible light-induced palladium-catalyzed homologative three-component synthesis of
allylic amines has been developed. This protocol proceeds via a unique mechanism …

The stereodivergent synthesis of allene compounds bearing α, β‐adjacent central chiralities
has been realized via the Pd/Cu‐catalyzed dynamic kinetic asymmetric alkylation of racemic …

Branched allylic esters and carboxylates are fundamental motifs prevalent in natural
products and drug molecules. The direct allylic C–H oxygenation of internal alkenes …

Fluorinated amino acids and related peptides/proteins have been found widespread
applications in pharmaceutical and agricultural compounds. However, strategies for …

Developing new strategies to enable chemo-and regioselective reductions is an important
topic in chemical research. Herein, an efficient and regioselective Pd/IPrBIDEA-catalyzed …

Multicomponent reactions that involve interception of onium ylides through Aldol, Mannich,
and Michael addition with corresponding bench-stable acceptors have demonstrated broad …

Stereoselective carbon-carbon bond formation via palladium-catalyzed asymmetric allylic
alkylation is a crucial strategy to access chiral natural products and active pharmaceutical …