Over the past few years, CuH‐catalyzed hydroamination has been discovered and
developed as a robust and conceptually novel approach for the synthesis of …

In addition to the appealing synthetic transformations that cyclopropanes present, they are
also part of larger molecular structures that possess a wide range of biological properties …

Here we report a ternary catalyst system for the intramolecular hydroamidation of
unactivated olefins using simple N-aryl amide derivatives. Amide activation in these …

Catalysis by small molecules (≤ 1000 Da, 10− 9 m) that are capable of binding and
activating substrates through attractive, noncovalent interactions has emerged as an …

The cation− π interaction is an attractive noncovalent interaction between a cation and a π
system. Due to the stronger interaction energy than those of the other π interactions, such as …

A visible‐light photocatalytic generation of N‐centered hydrazonyl radicals has been
accomplished for the first time. This approach allows efficient intramolecular addition of …

While olefin amination with aminium radical cations is a classical method for C–N bond
formation, catalytic variants that utilize simple 2° amine precursors remain largely …

An enantioselective, radical-based method for the intramolecular hydroamination of alkenes
with sulfonamides is reported. These reactions are proposed to proceed via N-centered …

This review provides an overview of synthetic transformations that have been performed by
both electro-and photoredox catalysis. Both toolboxes are evaluated and compared in their …

This Perspective article outlines some of the recent advancements completed in the
development of (chiral) metal-free and late-transition metal catalysts for the inter-and …