Hybrid polyoxometalates as post-functionalization platforms: from fundamentals to emerging applications

AV Anyushin, A Kondinski, TN Parac-Vogt - Chemical Society Reviews, 2020 - pubs.rsc.org
Polyoxometalates (POMs) represent an important group of metal–oxo nanoclusters, typically
comprised of early transition metals in high oxidation states (mainly V, Mo and W). Many …

[HTML][HTML] Overview of Wells-Dawson Polyoxometalates: from structure and functionalization to application

D Nowicka, N Vadra, E Wieczorek-Szweda… - Coordination Chemistry …, 2024 - Elsevier
Abstract Wells-Dawson polyoxometalates (WD POMs) are an important subgroup within the
diverse family of POMs. In the last two decades, there has been remarkable progress in the …

Shining a light on the photo-sensitisation of organic–inorganic hybrid polyoxometalates

JM Cameron, DJ Wales, GN Newton - Dalton Transactions, 2018 - pubs.rsc.org
Finding new ways of using visible light (or, more specifically, solar irradiation) to drive
commercially significant and/or challenging chemical processes is an ongoing research …

Tuning the electronic structure of organic–inorganic hybrid polyoxometalates: The crucial role of the covalent linkage

AJ Kibler, GN Newton - Polyhedron, 2018 - Elsevier
The covalent organofunctionalization of polyoxometalates (POMs) has been widely used to
both control and enhance their redox properties, particularly for applications in catalysis …

Versatile post-functionalisation strategy for the formation of modular organic–inorganic polyoxometalate hybrids

DES Marcano, MA Moussawi, AV Anyushin… - Chemical …, 2022 - pubs.rsc.org
Hybrid structures incorporating different organic and inorganic constituents are emerging as
a very promising class of materials since they synergistically combine the complementary …

Directing the solid-state photochromic and luminescent behaviors of spiromolecules with Dawson and Anderson polyoxometalate units

H Dridi, A Boulmier, P Bolle, A Dolbecq… - Journal of Materials …, 2020 - pubs.rsc.org
A series of three new polyoxometalate/spiromolecule compounds–including the (TBA) 3
[AlMo6-SN](SN= spironaphthoxazine) and (TBA) 3 [AlMo6-SP](SP= spiropyran) Anderson …

Two Polyoxometalate‐Based Hybrid Compounds Modified by Iron Schiff Base Complexes: Syntheses, Crystal structures, Cyclic Voltametric Studies and Nonlinear …

JL Wang, MX Yang, YX Zhu, JP Cao, ZY Du… - …, 2021 - Wiley Online Library
Two new polyoxometalate (POM)‐based hybrid compounds modified by a Schiff base,[Fe
(DAPSC)(H2O) 2] 2 [HPMo2VMo10VIO40]⋅ 5H2O (1) and [Fe (DAPSC)(H2O)] 2 …

Photoactive polyoxometalate/DASA covalent hybrids for photopolymerization in the visible range

A Boulmier, M Haouas, S Tomane… - … A European Journal, 2019 - Wiley Online Library
The synthesis of TBA‐DASA‐POM‐DASA, the first photoactive covalent hybrid
polyoxometalate (POM) incorporating a donor–acceptor Stenhouse adduct (DASA) reverse …

Interplay between the amphipathic polyoxometalate interactions in solution and at solid–liquid interfaces: a toolbox for the technical application

M Glöβ, R Pütt, M Moors, E Kentzinger… - Nanoscale, 2019 - pubs.rsc.org
The far-reaching interplay between the speciation of polyoxometalates (POMs) in the liquid
phase and the POM adsorption characteristics on substrate surfaces yet remains to be …

Photocatalytic degradation of textile dye X-3B using TiW11Ti/SiO2 hybrid materials

L Ai, D Zhang, Q Wang, J Yan, Q Wu - Catalysis Communications, 2019 - Elsevier
Various photocatalysts composed of undecatungstotitanotitanic heteropoly acid (H 4 [Ti (H 2
O) TiW 11 O 39]· 7H 2 O) loaded on silica (TiW 11 Ti/SiO 2) were prepared by sol-gel …