Perspectives on atmospheric CO2 fixation in inorganic and biomimetic structures

NJ English, MM El-Hendawy, DA Mooney… - Coordination Chemistry …, 2014 - Elsevier
In this review, we examine the fixation of atmospheric carbon dioxide, primarily in inorganic
and biomimetic structures, the latter of which can be seen to be inspired by Nature. We …

Effect of cyanato, azido, carboxylato, and carbonato ligands on the formation of cobalt (II) polyoxometalates: characterization, magnetic, and electrochemical studies of …

L Lisnard, P Mialane, A Dolbecq… - … A European Journal, 2007 - Wiley Online Library
Five CoII silicotungstate complexes are reported. The centrosymmetric heptanuclear
compound K20 [{(B‐β‐SiW9O33 (OH))(β‐SiW8O29 (OH) 2) Co3 (H2O)} 2Co (H2O) 2]⋅ 47 …

Robust cluster building unit: Icosanuclear heteropolyoxocopperate templated by carbonate

FL Liu, B Kozlevčar, P Strauch… - … A European Journal, 2015 - Wiley Online Library
The encapsulation of carbonate derived from atmospheric CO2 has resulted in an
icosanuclear heteropolyoxocopperate, isolated as a metal–organic 1D chain, 2D sheet, or …

Ring‐Size‐Modulated Reactivity of Putative Dicobalt‐Bridging Nitrides: C− H Activation versus Phosphinimide Formation

P Cui, Q Wang, SP McCollom, BC Manor… - Angewandte …, 2017 - Wiley Online Library
Dicobalt complexes supported by flexible macrocyclic ligands were used to target the
generation of the bridging nitrido species [(nPDI2) Co2 (μ‐N)(PMe3) 2] 3+(PDI= 2, 6 …

CO2 Fixation and Transformation by a Dinuclear Copper Cryptate under Acidic Conditions

JM Chen, W Wei, XL Feng, TB Lu - Chemistry–An Asian Journal, 2007 - Wiley Online Library
CO2 fixation and transformation by metal complexes continuously receive attention from the
viewpoint of carbon resources and environmental concerns. We found that the dinuclear …

A Trinuclear Copper(II) Cryptate and Its μ3‐CO3 Cascade Complex: Thermodynamics, Structural and Magnetic Properties

P Mateus, R Delgado, F Lloret, J Cano… - … A European Journal, 2011 - Wiley Online Library
Abstract The 2, 4, 6‐triethylbenzene‐capped hexaamine macrobicycle with pyridyl spacers
(pyr) was able to coordinate three copper (II) ions within its cavity. Potentiometric studies …

Realization of Unusual Ligand Binding Motifs in Metalated Container Molecules: Synthesis, Structures, and Magnetic Properties of the Complexes [(LMe) Ni2 (μ‐L′)] …

J Hausmann, MH Klingele, V Lozan… - … A European Journal, 2004 - Wiley Online Library
A series of dinickel (ii) complexes with the 24-membered macrocyclic hexaazadithiophenol
ligand H2LMe was prepared and examined. The doubly deprotonated form (LMe) 2À forms …

CuII Coordination Chemistry of Patellamide Derivatives: Possible Biological Functions of Cyclic Pseudopeptides

P Comba, N Dovalil, LR Gahan… - … A European Journal, 2012 - Wiley Online Library
Two synthetic derivatives of the naturally occurring cyclic pseudooctapeptides patellamide A–
F and ascidiacyclamide, that is, H4pat2, H4pat3, as well as their CuII complexes are …

cis‐Bromination of Encapsulated Alkenes

G Steinfeld, V Lozan, B Kersting - … Chemie International Edition, 2003 - Wiley Online Library
Metalated container molecules are currently attracting much interest, since their properties
are often different from those of their constituent components.[1–3] Several groups have …

Carboxylate and alkyl carbonate coordination at the hydrophobic binding site of redox-active dicobalt amine thiophenolate complexes

B Kersting, G Steinfeld - Inorganic chemistry, 2002 - ACS Publications
A series of new dicobalt complexes of the permethylated macrocyclic hexaamine
dithiophenolate ligand H2LMe have been prepared and investigated in the context of ligand …