Improving f-element single molecule magnets

ST Liddle, J van Slageren - Chemical Society Reviews, 2015 - pubs.rsc.org
Ever since the discovery that certain manganese clusters retain their magnetisation for
months at low temperatures, there has been intense interest in molecular nanomagnets …

Direct measurement of dysprosium (III) dysprosium (III) interactions in a single-molecule magnet

E Moreno Pineda, NF Chilton, R Marx, M Dörfel… - Nature …, 2014 - nature.com
Lanthanide compounds show much higher energy barriers to magnetic relaxation than 3d-
block compounds, and this has led to speculation that they could be used in molecular …

Metal–Halide Covalency, Exchange Coupling, and Slow Magnetic Relaxation in Triangular (CpiPr5)3U3X6 (X = Cl, Br, I) Clusters

DJ Lussier, E Ito, KR McClain, PW Smith… - Journal of the …, 2024 - ACS Publications
The actinide elements are attractive alternatives to transition metals or lanthanides for the
design of exchange-coupled multinuclear single-molecule magnets. However, the synthesis …

Thermostability and photoluminescence of Dy (III) single-molecule magnets under a magnetic field

Y Bi, C Chen, YF Zhao, YQ Zhang, SD Jiang… - Chemical …, 2016 - pubs.rsc.org
A series of compounds [ADyL4]·[solvent] composed of a dysprosium (III) ion coordinated by
four chelated naphthyridine-like ligands (L= 4-hydroxy-8-methyl-1, 5-naphthyridine-3 …

A single-ion magnet building block strategy toward Dy 2 single-molecule magnets with enhanced magnetic performance

D Shao, PP Sahu, WJ Tang, YL Zhang, Y Zhou… - Dalton …, 2022 - pubs.rsc.org
A molecular dysprosium (III) complex [Dy (DClQ) 3 (H2O) 2](1) was used as a building unit
for the construction of lanthanide SMMs, leading to the isolation of two dinuclear Dy (III) …

Magnetic behaviour of a spin-canted asymmetric lanthanide quinolate trimer

L Batista, S Paul, C Molina-Jirón, JA Jaén… - Dalton …, 2024 - pubs.rsc.org
An asymmetrical dysprosium trimer with a molecular formula of [Dy3 (hq) 7 (hqH)(NO3) 2
(H2O)] was obtained through a reflux reaction employing as starting material Dy (NO3) 3 …

Luminescence, magnetocaloric effect and single-molecule magnet behavior in lanthanide complexes based on a tridentate ligand derived from 8-hydroxyquinoline

HY Shen, WM Wang, YX Bi, HL Gao, S Liu… - Dalton Transactions, 2015 - pubs.rsc.org
A new family of lanthanide complexes,[Ln2 (hfac) 4L2](Ln= Eu (1), Gd (2), Tb (3), Dy (4), Ho
(5), Er (6), Lu (7); hfac= hexafluoroacetylacetonate, HL= 2-(2′-benzothiazole)-8 …

Efficient synthetic route to heterobimetallic trinuclear complexes [Ln–Mn–Ln] and their single molecule magnetic properties

NF Ghazali, KR Vignesh, W Phonsri, KS Murray… - Dalton …, 2022 - pubs.rsc.org
A series of mononuclear lanthanoidate complexes isolated as [Bu4N][Ln (QCl4)] 1Ln (QCl=
5-chloro-8-quinolinolate; Ln= Eu, Gd, Tb, Dy, Ho, and Er) have been prepared …

Tuning magnetic anisotropy via terminal ligands along the Dy⋯ Dy orientation in novel centrosymmetric [Dy 2] single molecule magnets

M Kong, X Feng, J Wang, YQ Zhang, Y Song - Dalton Transactions, 2021 - pubs.rsc.org
Four DyIII complexes,[Dy2 (NO3) 4 (L) 2 (H2O) 2]· 2MeCN (1),[Dy2 (NO3) 4 (L) 2 (H2O) 2]· 2
(NO3)· DMBD· 2MeOH (2),[Dy2 (NO3) 4 (L) 2 (TPO) 2]· 2MeCN (3) and [Dy2 (L′) 6 (H2O) …

Mononuclear lanthanide (III)-oxamate complexes as new photoluminescent field-induced single-molecule magnets: solid-state photophysical and magnetic properties

RCA Vaz, IO Esteves, WXC Oliveira, J Honorato… - Dalton …, 2020 - pubs.rsc.org
Implementing additional optical (luminescent) properties into the well-known class of single-
molecule magnets (SMMs) is considered as a promising route toward obtaining the next …