An automatic variable laser attenuator for IRMPD spectroscopy and analysis of power-dependence in fragmentation spectra
Infrared ion spectroscopy (IRIS) requires reproducibility and standard protocols in order to
be fully appreciated as an analytical tool. An important parameter in IRIS measurements is …
be fully appreciated as an analytical tool. An important parameter in IRIS measurements is …
Electronic structure theory to decipher the chemical bonding in actinide systems
JP Dognon - Coordination Chemistry Reviews, 2017 - Elsevier
The chemical bonding in actinide compounds is usually analysed by inspecting the shape
and the occupation of the orbitals or by calculating bond orders which are based on orbital …
and the occupation of the orbitals or by calculating bond orders which are based on orbital …
Organolanthanide Complexes Containing Ln–CH3 σ-bonds: Unexpectedly Similar Hydrolysis Rates for Trivalent and Tetravalent Organocerium
Z Shafi, JK Gibson - Inorganic Chemistry, 2023 - ACS Publications
We report the gas-phase preparation, isolation, and reactivity of a series of
organolanthanides featuring the Ln–CH3 bond. The complexes are formed by …
organolanthanides featuring the Ln–CH3 bond. The complexes are formed by …
Unusual Actinyl Complexes with a Redox-Active N, S-Donor Ligand
Understanding the fundamental chemistry of soft N, S-donor ligands with actinides across
the series is critical for separation science toward sustainable nuclear energy. This task is …
the series is critical for separation science toward sustainable nuclear energy. This task is …
A Thorium (IV) metallacyclopropyne complex
X Chen, S Wan, Q Wang, Y Gong - Nature Communications, 2024 - nature.com
Actinide metallacyclic chemistry has been of interest due to its involvement in various
chemical processes. However, fundamental understanding on the key species, actinide …
chemical processes. However, fundamental understanding on the key species, actinide …
Dual-Ligand Strategy for the Preparation of Gas-Phase Uranyl (VI) Benzyne Complexes from Uranyl (VI) Benzoates
Z Xiong, M Yang, X Chen, Y Gong - Inorganic Chemistry, 2023 - ACS Publications
The uranyl (VI) benzyne complex (η2-C6H4) UO2Cl–was prepared in the gas phase by
electrospray ionization mass spectrometry coupled with collision-induced dissociation. It …
electrospray ionization mass spectrometry coupled with collision-induced dissociation. It …
Mass spectrometric and theoretical study on the formation of uranyl hydride from uranyl carboxylate
Z Xiong, X Chen, Y Gong - Physical Chemistry Chemical Physics, 2021 - pubs.rsc.org
Uranyl hydride in the form of HUO2Cl2− was prepared upon collision-induced dissociation
of (RCO2) UO2Cl2−(R= H, CH3CH2, CH3CH2CH2, CH3CHCH,(CH3) 2CH, C5H9, C6H11 …
of (RCO2) UO2Cl2−(R= H, CH3CH2, CH3CH2CH2, CH3CHCH,(CH3) 2CH, C5H9, C6H11 …
Gas-phase synthesis and structure of thorium benzyne complexes
X Chen, Z Xiong, M Yang, Y Gong - Chemical Communications, 2022 - pubs.rsc.org
The thorium benzyne complex (η2-C6H4) ThCl3− was synthesized in the gas phase through
consecutive decarboxylation and dehydrochlorination from the (C6H5CO2) ThCl4 …
consecutive decarboxylation and dehydrochlorination from the (C6H5CO2) ThCl4 …
Cleaving off uranyl oxygens through chelation: A mechanistic study in the gas phase
Recent efforts to activate the strong uranium–oxygen bonds in the dioxo uranyl cation have
been limited to single oxo-group activation through either uranyl reduction and …
been limited to single oxo-group activation through either uranyl reduction and …
Gas phase reactions of ions derived from anionic uranyl formate and uranyl acetate complexes
The speciation and reactivity of uranium are topics of sustained interest because of their
importance to the development of nuclear fuel processing methods, and a more complete …
importance to the development of nuclear fuel processing methods, and a more complete …