Atomically precise colloidal metal nanoclusters and nanoparticles: fundamentals and opportunities

R Jin, C Zeng, M Zhou, Y Chen - Chemical reviews, 2016 - ACS Publications
Colloidal nanoparticles are being intensely pursued in current nanoscience research.
Nanochemists are often frustrated by the well-known fact that no two nanoparticles are the …

Quantum mechanical studies of large metal, metal oxide, and metal chalcogenide nanoparticles and clusters

A Fernando, KLDM Weerawardene… - Chemical …, 2015 - ACS Publications
Metal, metal oxide, and metal chalcogenide materials have a wide variety of applications.
For example, many metal clusters and nanoparticles are used as catalysts for reactions …

A critical size for emergence of nonbulk electronic and geometric structures in dodecanethiolate-protected Au clusters

Y Negishi, T Nakazaki, S Malola… - Journal of the …, 2015 - ACS Publications
We report on how the transition from the bulk structure to the cluster-specific structure occurs
in n-dodecanethiolate-protected gold clusters, Au n (SC12) m. To elucidate this transition …

Crystal Structure of Barrel-Shaped Chiral Au130(p-MBT)50 Nanocluster

Y Chen, C Zeng, C Liu, K Kirschbaum… - Journal of the …, 2015 - ACS Publications
We report the structure determination of a large gold nanocluster formulated as Au130 (p-
MBT) 50, where p-MBT is 4-methylbenzenethiolate. The nanocluster is constructed in a four …

Mechanistic exploration and controlled synthesis of precise thiolate-gold nanoclusters

N Goswami, Q Yao, T Chen, J Xie - Coordination Chemistry Reviews, 2016 - Elsevier
Well-defined thiolate-gold nanoclusters (generally described as Au n (SR) m NCs, where “n”
and “m” are the numbers of gold atoms and thiolate ligands (–SR), respectively), comprise a …

Recent advances in the synthesis, characterization, and biomedical applications of ultrasmall thiolated silver nanoclusters

K Zheng, X Yuan, N Goswami, Q Zhang, J Xie - RSC advances, 2014 - pubs.rsc.org
With ultrasmall particle sizes of∼ 1 nm, thiolate-protected silver nanoclusters (or thiolated
Ag NCs) have recently emerged as an attractive frontier of nanoparticle research because of …

Au25(SEt)18, a Nearly Naked Thiolate-Protected Au25 Cluster: Structural Analysis by Single Crystal X-ray Crystallography and Electron Nuclear Double Resonance

T Dainese, S Antonello, JA Gascon, F Pan… - ACS Nano, 2014 - ACS Publications
X-ray crystallography has been fundamental in discovering fine structural features of
ultrasmall gold clusters capped by thiolated ligands. For still unknown structures, however …

Synthesizing Photoluminescent Au28(SCH2Ph‐tBu)22 Nanoclusters with Structural Features by Using a Combined Method

J Dong, Z Gan, W Gu, Q You, Y Zhao, J Zha… - Angewandte …, 2021 - Wiley Online Library
We present a method for atomically precise nanocluster synthesis. As an illustration, we
introduced the reducing‐ligand induction combined method and synthesized a novel …

Amphiphilic Block Copolymer-Guided in Situ Fabrication of Stable and Highly Controlled Luminescent Copper Nanoassemblies

T Zhou, J Zhu, L Gong, L Nong… - Journal of the American …, 2019 - ACS Publications
Assembling instable ultrasmall nanoparticles (NPs) into uniform nanoarchitectures with
excellent stability and controllability in aqueous solution is still challenging. Herein, taking …

Atomic-level separation of thiolate-protected metal clusters

Y Negishi, S Hashimoto, A Ebina, K Hamada… - Nanoscale, 2020 - pubs.rsc.org
Fine metal clusters have attracted much attention from the viewpoints of both basic and
applied science for many years because of their unique physical/chemical properties and …