[HTML][HTML] Towards a new class of stimuli-responsive polymer-based materials–Recent advances and challenges

A Bratek-Skicki - Applied Surface Science Advances, 2021 - Elsevier
The rapidly-growing field of polymer stimuli-responsive materials (smart materials) resulted
in many advances in designing and developing multi-functional systems, novel …

Microgels react to force: mechanical properties, syntheses, and force-activated functions

MF Schulte, E Izak-Nau, S Braun, A Pich… - Chemical Society …, 2022 - pubs.rsc.org
Microgels are colloidal polymer networks with high molar mass and properties between rigid
particles, flexible macromolecules, and micellar aggregates. Their unique stimuli …

Surface‐bound microgels for separation, sensing, and biomedical applications

CC Cutright, JL Harris, S Ramesh… - Advanced Functional …, 2021 - Wiley Online Library
This study presents a comprehensive survey of microgel‐coated materials and their
functional behavior, describing the complex interplay between the physicochemical and …

Nanostructures, thermoresponsiveness, and assembly mechanism of hydrogel microspheres during aqueous free-radical precipitation polymerization

Y Nishizawa, H Minato, T Inui, T Uchihashi, D Suzuki - Langmuir, 2020 - ACS Publications
Although techniques to produce uniformly sized hydrogel microspheres (microgels) by
aqueous free-radical precipitation polymerization are well established, the details of the …

Amphiphilic PVCL/TBCHA microgels: From synthesis to characterization in a highly selective solvent

RA Gumerov, E Gau, W Xu, A Melle, SA Filippov… - Journal of colloid and …, 2020 - Elsevier
Thermoresponsive copolymer microgels based on the biocompatible monomer N-
vinylcaprolactam (VCL) and the hydrophobic comonomer 4-tert-butylcyclohexylacrylate …

Copolymerization kinetics of dopamine methacrylamide during PNIPAM microgel synthesis for increased adhesive properties

S Forg, A Karbacher, Z Ye, X Guo, R von Klitzing - Langmuir, 2022 - ACS Publications
Combining stimuli-responsive properties of gels with adhesive properties of mussels is
highly interesting for a large field of applications as, eg, in life science. Therefore, the …

Molecular dynamics simulations of ideal living polymerization: Terminal model and kinetic aspects

W Li - The Journal of Physical Chemistry B, 2023 - ACS Publications
Living polymerization is an important synthetic approach to achieving precise control of
synthesized polymers, which is crucial for their applications. The molecular weight …

Microphase separation of stimuli-responsive interpenetrating network microgels investigated by scattering methods

EY Kozhunova, VY Rudyak, X Li, M Shibayama… - Journal of Colloid and …, 2021 - Elsevier
Polymer stimuli-responsive microgels find their use in various applications. The knowledge
of its internal structure is of importance for further improvement and expanding the scope …

The fuzzy sphere morphology is responsible for the increase in light scattering during the shrinkage of thermoresponsive microgels

E Ponomareva, B Tadgell, M Hildebrandt, M Krüsmann… - Soft Matter, 2022 - pubs.rsc.org
Thermoresponsive microgels undergo a volume phase transition from a swollen state under
good solvent conditions to a collapsed state under poor solvent conditions. The most …

Interplay of Spatial and Topological Defects in Polymer Networks

BR Argun, A Statt - ACS Engineering Au, 2024 - ACS Publications
Polymer networks are widely used in applications, and the formation of a network and its gel
point can be predicted. However, the effects of spatial and topological heterogeneity on the …