Transition Metal Complexes as Catalysts for the Electroconversion of CO2: An Organometallic Perspective

NW Kinzel, C Werlé, W Leitner - … Chemie International Edition, 2021 - Wiley Online Library
The electrocatalytic transformation of carbon dioxide has been a topic of interest in the field
of CO2 utilization for a long time. Recently, the area has seen increasing dynamics as an …

Chemistry of compounds based on 1, 2, 3-triazolylidene-type mesoionic carbenes

R Maity, B Sarkar - JACS au, 2021 - ACS Publications
Mesoionic carbenes (MICs) of the 1, 2, 3-triazolylidene type have established themselves as
a popular class of compounds over the past decade. Primary reasons for this popularity are …

Bridge Sites of Au Surfaces Are Active for Electrocatalytic CO2 Reduction

Z Tao, AJ Pearce, JM Mayer… - Journal of the American …, 2022 - ACS Publications
Prior in situ attenuated total reflectance Fourier transform infrared (ATR–FTIR) studies of
electrochemical CO2 reduction catalyzed by Au, one of the most selective and active …

Challenges and opportunities of atomic-scales reactive sites in thriving electrochemical CO2 reduction reaction

P Sun, S Liu, X Zheng, G Hu, Q Zhang, X Liu, G Zheng… - Nano Today, 2024 - Elsevier
Electrochemical carbon dioxide reduction reaction (ECO 2 RR) converts CO 2 into value-
added chemicals or fuels to realize carbon recycling as means to solve the problems of …

A Different Perspective on Tuning the Photophysical and Photochemical Properties: The Influence of Constitutional Isomers in Group 6 Carbonyl Complexes with …

T Bens, D Marhöfer, P Boden, ST Steiger… - Inorganic …, 2023 - ACS Publications
Exploring novel and existing design principles to tune the photochemical and photophysical
properties of transition-metal complexes is an important goal in contemporary research …

Rhenium chemistry–then and now

JR Dilworth - Coordination Chemistry Reviews, 2021 - Elsevier
The first section provides a background to the whole review. The second presents a
historical perspective of fundamental developments in rhenium chemistry from its discovery …

NIR‐Emissive Chromium (0), Molybdenum (0), and Tungsten (0) Complexes in the Solid State at Room Temperature

P Boden, P Di Martino‐Fumo, T Bens… - … A European Journal, 2021 - Wiley Online Library
The development of NIR emitters based on earth‐abundant elements is an important goal in
contemporary science. We present here Cr (0), Mo (0), and W (0) carbonyl complexes with a …

N‐Heterocyclic and Mesoionic Carbenes of Manganese and Rhenium in Catalysis

S Friães, S Realista, H Mourão… - European Journal of …, 2022 - Wiley Online Library
The use of N‐heterocyclic carbenes (NHCs) in manganese and rhenium catalysis is
underdeveloped in comparison to other transition metals. Herein, we cover the recent and …

Chromium (0) and Molydenum (0) Complexes with a Pyridyl-Mesoionic Carbene Ligand: Structural,(Spectro) electrochemical, Photochemical, and Theoretical …

T Bens, P Boden, P Di Martino-Fumo… - Inorganic …, 2020 - ACS Publications
This work reports on the synthesis and in-depth electrochemical and photochemical
characterization of two chromium (0) and molydenum (0) metal complexes with bidentate …

Improving the synthetic H 2 production catalyst design strategy with the neurotransmitter dopamine

S Ghorai, S Khandelwal, S Das, S Rai, S Guria… - Dalton …, 2023 - pubs.rsc.org
The strategic incorporation of the neurotransmitter dopamine around a cobaloxime core
resulted in excellent electrocatalytic (rate 8400 s− 1) and photocatalytic H2 production under …