Understanding specific ion effects and the Hofmeister series

KP Gregory, GR Elliott, H Robertson, A Kumar… - Physical Chemistry …, 2022 - pubs.rsc.org
Specific ion effects (SIE), encompassing the Hofmeister Series, have been known for more
than 130 years since Hofmeister and Lewith's foundational work. SIEs are ubiquitous and …

Molecular bases of protein halotolerance

G Graziano, A Merlino - Biochimica et Biophysica Acta (BBA)-Proteins and …, 2014 - Elsevier
Halophilic proteins are stable and function at high salt concentration. Understanding how
these molecules maintain their fold stable and avoid aggregation under harsh conditions is …

The effect of nanometre-scale structure on interfacial energy

JJ Kuna, K Voïtchovsky, C Singh, H Jiang… - Nature materials, 2009 - nature.com
Natural surfaces are often structured with nanometre-scale domains, yet a framework
providing a quantitative understanding of how nanostructure affects interfacial energy, γ SL …

Transesterification of soybean oil at room temperature using biowaste as catalyst; an experimental investigation on the effect of co-solvent on biodiesel yield

IB Laskar, T Deshmukhya, P Bhanja, B Paul, R Gupta… - Renewable Energy, 2020 - Elsevier
We report herein, Soybean oil was shaped to biodiesel using CaO as heterogeneous
catalyst and acetone as cosolvent by employing transesterification reaction at room …

The transport of carbon and hydrogen in subducted oceanic crust: An experimental study to 5 GPa

S Poli, E Franzolin, P Fumagalli, A Crottini - Earth and Planetary Science …, 2009 - Elsevier
Carbon and hydrogen residence time in the Earth's interior is controlled by complex phase
equilibria attained in the subduction zone environment. Carbonic fluid/melts are highly …

On the mechanism of cold denaturation

G Graziano - Physical Chemistry Chemical Physics, 2014 - pubs.rsc.org
A theoretical rationalization of the occurrence of cold denaturation for globular proteins was
devised, assuming that the effective size of water molecules depends upon temperature [G …

Effects of moisture and salinity on methane adsorption in kerogen: a molecular simulation study

J Zhou, Q Mao, KH Luo - Energy & Fuels, 2019 - ACS Publications
The adsorption characteristics of methane in shales play a critical role in the assessment of
shale gas resources. The microscopic adsorption mechanism of methane considering the …

Scaled charges at work: Salting out and interfacial tension of methane with electrolyte solutions from computer simulations

S Blazquez, IM Zeron, MM Conde, JLF Abascal… - Fluid Phase …, 2020 - Elsevier
The solubility of methane in water decreases when a small amount of salt is present. This is
usually denoted as the salting out effect (ie, the methane is expelled from the solution when …

Effects of moisture, salinity and ethane on the competitive adsorption mechanisms of CH4/CO2 with applications to coalbed reservoirs: A molecular simulation study

J Li, Y Wang, Z Chen, SS Rahman - Journal of Natural Gas Science and …, 2021 - Elsevier
Injection of carbon dioxide (CO 2) into coal seam gas reservoirs has been considered one of
the most popular approaches to enhance methane (CH 4) production. However, many …

Free-energy decomposition of salt effects on the solubilities of small molecules and the role of excluded-volume effects

S Hervø-Hansen, D Lin, K Kasahara… - Chemical Science, 2024 - pubs.rsc.org
The roles of cations and anions are different in the perturbation on solvation, and thus, the
analyses of the separated contributions from cations and anions are useful to establish …