Proton-Coupled Electron Transfer at the Pu5+/4+ Couple
KS Otte, JE Niklas, CM Studvick… - Journal of the …, 2024 - ACS Publications
The synthesis and solution and solid-state characterization of [Pu4+ (NPC) 4], 1-
Pu,(NPC=[NP t Bu (pyrr) 2]−; t Bu= C (CH3) 3; pyrr= pyrrolidinyl) and [Pu3+ (NPC) 4][K (2.2 …
Pu,(NPC=[NP t Bu (pyrr) 2]−; t Bu= C (CH3) 3; pyrr= pyrrolidinyl) and [Pu3+ (NPC) 4][K (2.2 …
Discovery of two Na+-centered Silverton-type polyoxometalates {NaM 12 O 42}(M= Mo, W)
R Wan, Z Liu, X Ma, H Li, P Ma, C Zhang… - Chemical …, 2021 - pubs.rsc.org
Two new members of highly charged Silverton archetype [NaM12O42] 11− were
demonstrated in the 3D POM-based frameworks Na3 [NaM12O42 (Ru (DMSO) 3) 4]· 13H2O …
demonstrated in the 3D POM-based frameworks Na3 [NaM12O42 (Ru (DMSO) 3) 4]· 13H2O …
Coordination chemistry of 2, 2′-biphenylenedithiophosphinate and diphenyldithiophosphinate with U, Np, and Pu
New members of the dithiophosphinic acid family of potential actinide extractants were
prepared: heterocyclic 2, 2′-biphenylenedithiophosphinic acids of stoichiometry HS2P …
prepared: heterocyclic 2, 2′-biphenylenedithiophosphinic acids of stoichiometry HS2P …
Expansion of the structural diversity of f-element bearing molybdate iodates: Synthesis, structures, and optical properties
Expanding the family of f-element bearing molybdate iodates via hydrothermal reactions has
yielded ten new rare-earth molybdate iodates with two distinct phases, Ln (MoO2)(IO3) 4 …
yielded ten new rare-earth molybdate iodates with two distinct phases, Ln (MoO2)(IO3) 4 …
Targeting complex plutonium oxides by combining crystal chemical reasoning with density-functional theory calculations: the quaternary plutonium oxide Cs 2 PuSi 6 …
The stability of the novel Pu (IV) silicate, Cs2PuSi6O15, was predicted from a combination of
crystal chemical reasoning and DFT calculations and confirmed by its synthesis via flux …
crystal chemical reasoning and DFT calculations and confirmed by its synthesis via flux …
Molybdenum Disorder in Hydrated Sedovite, Ideally U(MoO4)2·nH2O, a Microporous Nanocrystalline Mineral Characterized by Three-Dimensional Electron …
Sedovite, U4+ (Mo6+ O4) 2· n H2O, is reported as being one of the earliest supergene
minerals formed of the secondary zone. The difficulty of isolating enough pure material limits …
minerals formed of the secondary zone. The difficulty of isolating enough pure material limits …
Synthesis and structure of dodecamolybdates of tetravalent cerium, thorium, uranium, neptunium, and plutonium
IA Charushnikova, AV Gogolev, MS Grigor'ev… - Radiochemistry, 2016 - Springer
A series of isostructural compounds of the composition Na 7 H [EMo 12 O 42]· 12H 2 O,
where E (IV)= Ce, Th, U, Np, or Pu, were synthesized and structurally characterized. In the …
where E (IV)= Ce, Th, U, Np, or Pu, were synthesized and structurally characterized. In the …
Origins of the odd optical observables in plutonium and americium tungstates
A series of trivalent f-block tungstates, MW2O7 (OH)(H2O)(M= La, Ce, Pr, Nd, and Pu) and
AmWO4 (OH), have been prepared in crystalline form using hydrothermal methods. Both …
AmWO4 (OH), have been prepared in crystalline form using hydrothermal methods. Both …
[PDF][PDF] Synthetic Exploration of F-Element Borates and Plumbites
JT Stritzinger - 2015 - diginole.lib.fsu.edu
Despite their discovery during the 1940's, there are still many unanswered questions
surrounding the elements past uranium, or transuranic elements. In the recent years more …
surrounding the elements past uranium, or transuranic elements. In the recent years more …
[PDF][PDF] Précipitation des molybdates mixtes zirconium-cérium/plutonium en milieu aqueux HNO3
MA Ayral - 2017 - theses.fr
Résumé-Abstract Depuis 1993, un phénomène de précipitation mettant en jeu le molybdène
et le zirconium (produits de fission) conduit à l'encrassement des équipements de …
et le zirconium (produits de fission) conduit à l'encrassement des équipements de …