Mechanistic insights on Zn (II)− Co (III) double metal cyanide-catalyzed ring-opening polymerization of epoxides

CH Tran, LTT Pham, Y Lee, HB Jang, S Kim, I Kim - Journal of Catalysis, 2019 - Elsevier
Electron donating complexing agents (CAs) are one of the key components to achieve active
Zn (II)–Co (III) double metal cyanide (DMC) catalysts for the ring-opening polymerization …

Hydrolysis of vegetable oils and fats to fatty acids over solid acid catalysts

JK Satyarthi, D Srinivas, P Ratnasamy - Applied Catalysis A: General, 2011 - Elsevier
Solid Fe-Zn double-metal cyanide (DMC) complexes exhibit high catalytic activity for
hydrolysis of edible and non-edible vegetable oils and animal fat. In a batch reaction …

Zn–Co double metal cyanides as heterogeneous catalysts for hydroamination: A structure–activity relationship

A Peeters, P Valvekens, R Ameloot, G Sankar… - ACS …, 2013 - ACS Publications
Zn–Co double metal cyanide (DMC) materials are effective heterogeneous catalysts for
intermolecular hydroaminations. Using the reaction of 4-isopropylaniline with …

Mesoporous titania‐iron (III) Oxide with nanoscale porosity and high catalytic activity for the synthesis of β‐amino alcohols and benzimidazole derivatives

S Roy, B Banerjee, N Salam, A Bhaumik… - …, 2015 - Wiley Online Library
Abstract A mesoporous TiO2‐Fe2O3 mixed oxide material (MTF‐1E) with nanoscale
porosity and a high BET surface area was synthesized using sodium dodecyl sulfate (SDS) …

Effects of method of preparation on catalytic activity of Co–Zn double-metal cyanide catalysts for copolymerization of CO2 and epoxide

J Sebastian, D Srinivas - Applied Catalysis A: General, 2014 - Elsevier
Co–Zn double-metal cyanide (DMC) complexes are well-known catalysts for ring-opening
polymerization of epoxides and co-polymerization of CO 2 and epoxides. This work provides …

Kinetic and mechanistic study of heterogeneous double metal cyanide-catalyzed ring-opening multibranching polymerization of glycidol

CH Tran, MW Lee, SA Kim, HB Jang, I Kim - Macromolecules, 2020 - ACS Publications
Polyglycidols of tunable degree of branching (DB) have been synthesized via ring-opening
multibranching polymerization (ROMBP) of glycidol in the absence of any initiators using …

Aminolysis of epoxides catalyzed by three-dimensional, mesoporous titanosilicates, Ti-SBA-12 and Ti-SBA-16

A Kumar, D Srinivas - Journal of catalysis, 2012 - Elsevier
The application of three-dimensional, mesoporous titanosilicates (Ti-SBA-12 and Ti-SBA-16)
as reusable, solid catalysts for the synthesis of a range of β-amino alcohols in high yields …

Highly enantioselective synthesis of chiral cyclic amino alcohols and conhydrine by ruthenium-catalyzed asymmetric hydrogenation

S Liu, JH Xie, W Li, WL Kong, LX Wang… - Organic Letters, 2009 - ACS Publications
A highly efficient enantio-and diastereoselective synthesis of chiral cis-β-N-alkyl/arylamino
cyclic alcohols has been realized by asymmetric hydrogenation of racemic α-amino cyclic …

Lewis acid double metal cyanide catalysts for hydroamination of phenylacetylene

A Peeters, P Valvekens, F Vermoortele… - Chemical …, 2011 - pubs.rsc.org
Double metal cyanides (DMCs) are highly active recyclable heterogeneous catalysts for
hydroamination of phenylacetylene with 4-isopropylaniline. The best hydroamination yields …

Porous Hexacyanometallate(III) Complexes as Catalysts in the Ring-Opening Copolymerization of CO2 and Propylene Oxide

G Penche, JR González-Velasco… - Catalysts, 2021 - mdpi.com
In this work, six porous hexacyanometallate complexes (Ni3 [Co (CN) 6] 2, Co3 [Co (CN) 6]
2, Fe3 [Co (CN) 6] 2, Ni3 [Fe (CN) 6] 2, Co3 [Fe (CN) 6] 2, Fe4 [Fe (CN) 6] 2) were …