Prebiotic astrochemistry and the formation of molecules of astrobiological interest in interstellar clouds and protostellar disks

SA Sandford, M Nuevo, PP Bera, TJ Lee - Chemical reviews, 2020 - ACS Publications
Despite the generally hostile nature of the environments involved, chemistry does occur in
space. Molecules are seen in environments that span a wide range of physical and chemical …

Exploiting photoionization reflectron time-of-flight mass spectrometry to explore molecular mass growth processes to complex organic molecules in interstellar and …

AM Turner, RI Kaiser - Accounts of Chemical Research, 2020 - ACS Publications
Conspectus This Account presents recent advances in our understanding on the formation
pathways of complex organic molecules (COMs) within interstellar analog ices on ice-coated …

Overview of desorption parameters of volatile and complex organic molecules-A systematic dig through the experimental literature

NFW Ligterink, M Minissale - Astronomy & Astrophysics, 2023 - aanda.org
Context. Many molecules observed in the interstellar medium are thought to result from the
thermal desorption of ices. Parameters such as the desorption energy and pre-exponential …

Efficient formation pathway of methyl formate: The role of OH radicals on ice dust

A Ishibashi, H Hidaka, Y Oba, A Kouchi… - The Astrophysical …, 2021 - iopscience.iop.org
Three structural isomers of the C 2 H 4 O 2 molecule, namely, methyl formate (MF; HCOOCH
3), acetic acid (CH 3 COOH), and glycolaldehyde (HOCH 2 CHO), have attracted …

Exploitation of synchrotron radiation photoionization mass spectrometry in the analysis of complex organics in interstellar model ices

C Zhu, H Wang, I Medvedkov, J Marks… - The Journal of …, 2022 - ACS Publications
Unravelling the generation of complex organic molecules (COMs) on interstellar
nanoparticles (grains) is essential in establishing predictive astrochemical reaction networks …

iCOM formation from radical chemistry: a mechanistic study from cryogenic matrix coupled with IR and EPR spectroscopies

A Gutiérrez-Quintanilla, Y Layssac… - Monthly Notices of …, 2021 - academic.oup.com
Interstellar complex organic molecules (iCOMs) have been identified in different interstellar
environments including star forming regions as well as cold dense molecular clouds …

Interstellar formation of glyceric acid [HOCH2CH(OH)COOH]—The simplest sugar acid

J Wang, JH Marks, RC Fortenberry, RI Kaiser - Science Advances, 2024 - science.org
Glyceric acid [HOCH2CH (OH) COOH]—the simplest sugar acid—represents a key molecule
in biochemical processes vital for metabolism in living organisms such as glycolysis …

A Photoionization Reflectron Time‐of‐Flight Mass Spectrometric Study on the Detection of Ethynamine (HCCNH2) and 2H‐Azirine (c‐H2CCHN)

AM Turner, S Chandra, RC Fortenberry… - …, 2021 - Wiley Online Library
Ices of acetylene (C2H2) and ammonia (NH3) were irradiated with energetic electrons to
simulate interstellar ices processed by galactic cosmic rays in order to investigate the …

Mechanistical study on the formation of hydroxyacetone (CH 3 COCH 2 OH), methyl acetate (CH 3 COOCH 3), and 3-hydroxypropanal (HCOCH 2 CH 2 OH) along …

J Wang, JH Marks, AM Turner, AA Nikolayev… - Physical Chemistry …, 2023 - pubs.rsc.org
We unravel, for the very first time, the formation pathways of hydroxyacetone
(CH3COCH2OH), methyl acetate (CH3COOCH3), and 3-hydroxypropanal …

Cyclopropenone (c-C3H2O) as a tracer of the nonequilibrium chemistry mediated by galactic cosmic rays in interstellar ices

NF Kleimeier, MJ Abplanalp, RN Johnson… - The Astrophysical …, 2021 - iopscience.iop.org
While gas-phase astrochemical reaction networks nicely replicate the abundance of
hydrogen-deficient organics like linear cyanopolyynes, pathways to complex organic …