Conspectus Heterometallic clusters with M–M bonds have significantly interested chemists
because of their attractive structures and synergistic effects in small-molecule activation and …

The coordination and organometallic chemistry of the f-elements, that is group 3, lanthanide,
and actinide ions, supported by nitrogen ligands, eg amides, imides, and nitrides, has …

Two‐electron oxidative addition is one of the most important elementary reactions for d‐
block transition metals but it is uncommon for f‐block elements. Here, we report the first …

Developing practical and mild strategies for the direct functionalization of white phosphorus
(P4) without chlorination is an appealing but formidable challenge. To this end, we report a …

Cooperative chemistry between two or more metal centres can show enhanced reactivity
compared to the monometallic fragments. Given the paucity of actinide–metal bonds …

Ligands are known to play a crucial role in the construction of complexes with metal–metal
bonds. Compared with metal–metal bonds involving d-block transition metals, knowledge of …

Developing practical strategies for the synthesis of organophosphorus compounds (OPCs)
from white phosphorus (P4) without the use of Cl2 and PCl3 remains a significant challenge …

Although examples of multiple bonds between actinide elements and main‐group elements
are quite common, studies of the multiple bonds between actinide elements and transition …

The development of practical and mild catalytic methods for the direct transformation of white
phosphorus into value-added organophosphorus compounds, without the hazardous …

Comprehensive Summary The strong oxophilicity of actinide complexes prevents their
applications in the transformation of oxygen‐containing substrates. Herein, we report the …