Organoboron reagents represent a unique class of compounds because of their utility in
modern synthetic organic chemistry, often affording unprecedented reactivity. The …

Past several decades have witnessed the great evolution of inert C–H bond functionalization
reactions as an emerging technique for synthesizing drug molecules, agrochemicals, and …

Hydrofunctionalization of alkenes and alkynes is increasingly important in preparing and
modifying carbon-centered organic molecules such as pharmaceuticals, agrochemicals, and …

The lack of mode for chirality recognition makes it particularly challenging to carry out
asymmetric transformations on E/Z-mixed minimally functionalized trisubstituted alkenes …

Abstract A remote C (sp3)− H bond asymmetric borylation of unactivated alkenes was
achieved by bimetallic relay catalysis. The reaction proceeded through reversible and …

Homoleptic lanthanide trisamides provide a simple and highly accessible bridge between
organolanthanide chemistry and the synthetic methodology community, and although they …

The structural diversity of sp3‐triorganometallic reagents enhances their potentiality in the
modular construction of molecular complexity in chemical synthesis. Despite significant …

A tungsten-catalyzed hydroboration of unactivated alkenes at distal C (sp3)–H bonds aided
by native directing groups is described herein. The method is characterized by its simplicity …

A MnI‐catalyzed hydroboration of terminal alkenes and a 1, 2‐diboration of terminal alkynes
with pinacolborane (HBPin) is described. For alkenes, anti‐Markovnikov hydroboration …

Site isolation of unstable catalytic species within a reticular material is an appealing strategy
for mitigating catalyst decomposition while creating catalysts with improved activity and …