Comparison of the magnetic anisotropy and spin relaxation phenomenon of dinuclear terbium (III) phthalocyaninato single-molecule magnets using the geometric spin …

T Morita, M Damjanović, K Katoh… - Journal of the …, 2018 - ACS Publications
Herein we report the synthesis and characterization of a dinuclear TbIII single-molecule
magnet (SMM) with two [TbPc2] 0 units connected via a fused-phthalocyaninato ligand. The …

Trigonal prismatic tris-pyridineoximate transition metal complexes: A Cobalt (II) compound with high magnetic anisotropy

AA Pavlov, SA Savkina, AS Belov… - Inorganic …, 2017 - ACS Publications
High magnetic anisotropy is a key property of paramagnetic shift tags, which are mostly
studied by NMR spectroscopy, and of single molecule magnets, for which magnetometry is …

Observability of paramagnetic NMR signals at over 10 000 ppm chemical shifts

JC Ott, EA Suturina, I Kuprov, J Nehrkorn… - Angewandte …, 2021 - Wiley Online Library
We report an experimental observation of 31P NMR resonances shifted by over 10 000 ppm
(meaning percent range, and a new record for solutions), and similar 1H chemical shifts, in …

Taking solution Proton NMR to its extreme: prediction and detection of a hydride resonance in an intermediate-spin iron complex

JC Ott, H Wadepohl, M Enders… - Journal of the American …, 2018 - ACS Publications
Guided by DFT based modeling the chemical shift range of a hydride resonance in the
proton nuclear magnetic resonance (NMR) spectrum of the intermediate-spin, square planar …

Probing Spin Crossover in a Solution by Paramagnetic NMR Spectroscopy

AA Pavlov, GL Denisov, MA Kiskin… - Inorganic …, 2017 - ACS Publications
Spin transitions in spin-crossover compounds are now routinely studied in the solid state by
magnetometry; however, only a few methods exist for studies in solution. The currently used …

Beyond Bleaney's Theory: Experimental and Theoretical Analysis of Periodic Trends in Lanthanide‐Induced Chemical Shift

EA Suturina, K Mason, CFGC Geraldes… - Angewandte …, 2017 - Wiley Online Library
A detailed analysis of paramagnetic NMR shifts in a series of isostructural lanthanide
complexes relavant to PARASHIFT contrast agents reveals unexpected trends in the …

A trigonal prismatic cobalt (II) complex as a single molecule magnet with a reduced contribution from quantum tunneling

AA Pavlov, DY Aleshin, SA Savkina, AS Belov… - …, 2019 - Wiley Online Library
Herein, we report a new trigonal prismatic cobalt (II) complex that behaves as a single
molecule magnet. The obtained zero‐field splitting, which is also directly accessed by THz …

Solvent-induced encapsulation of cobalt (II) ion by a boron-capped tris-pyrazoloximate

AS Belov, YZ Voloshin, AA Pavlov… - Inorganic …, 2020 - ACS Publications
Boron-cross-linked cobalt (II) pseudoclathrochelate was obtained by the template reaction of
2-acetylpyrazoloxime, phenylboronic acid, and a new DMF cobalt (II) solvato complex with a …

The chemistry of the carbon-transition metal double and triple bond: Annual survey covering the year 2017

JW Herndon - Coordination Chemistry Reviews, 2018 - Elsevier
This is a review of papers published in the year 2017 that focus on the synthesis, reactivity,
or properties of compounds containing a carbon-transition metal double or triple bond …

Ligand-Field Energy Splitting in Lanthanide-Based Single-Molecule Magnets by NMR Spectroscopy

M Hiller, S Krieg, N Ishikawa, M Enders - Inorganic chemistry, 2017 - ACS Publications
A method for the experimental determination of ligand-field (LF) energy splitting in
mononuclear lanthanide complexes, based purely on variable-temperature NMR …