Imidazolium Ionic Liquids (ILs) have been found to exhibit unusual nanostructuring behavior
below their glass transition temperatures (Tg), which is ascribed to rearrangements in …

Solution state Overhauser dynamic nuclear polarization (ODNP) has been studied for 60
years, but only in recent years has found applications of broad interest to biophysical …

Relaxation times were measured at X-band (9.5 GHz) at concentrations up to 20.8 mM for
two nitroxides that are widely used in Overhauser dynamic nuclear polarization (ODNP) …

Relaxation refers to the return to equilibrium by an unpaired electron spin system that is not
in thermal equilibrium. Readers who come to the field of EPR with a background in optical …

Ionic liquid (IL) glasses have recently drawn much interest as unusual media with unique
physicochemical properties. In particular, anomalous suppression of molecular mobility in …

1H spin-lattice relaxation experiments have been performed for a series of ionic liquids
including bis (trifluoromethanesulfonyl) imide anion and cations of a varying alkyl chain …

Unusual physicochemical properties of ionic liquids (ILs) open vistas for a variety of new
applications. Herewith, we investigate the influence of microviscosity and nanostructuring of …

In fluid solution, motion-dependent processes dominate electron spin-lattice relaxation for
nitroxides and semiquinones at frequencies between 250 MHz and 34 GHz. For triarylmethyl …

Abstract Saturation-recovery (SR)-EPR can determine electron spin–lattice relaxation rates
in liquids over a wide range of effective viscosity, making it especially useful for biophysical …

We report high-pressure (up to 50 MPa) ESR-spectroscopic investigations on the rotational
correlation times of the nitroxide radicals 2, 2, 6, 6-tetramethylpiperidine 1-oxyl (TEMPO), 4 …