FI Catalysts for olefin polymerization A comprehensive treatment

H Makio, H Terao, A Iwashita, T Fujita - Chemical reviews, 2011 - ACS Publications
1.1. General Overview Polyolefinic materials, exemplified by polyethylenes (PEs),
polypropylenes (PPs), and ethylene/R-olefin amorphous copolymers, display many notable …

High-performance olefin polymerization catalysts discovered on the basis of a new catalyst design concept

T Matsugi, T Fujita - Chemical Society Reviews, 2008 - pubs.rsc.org
This critical review highlights the “ligand oriented catalyst design concept”, a new catalyst
design concept for olefin polymerization that has led to the development of high-activity …

Recent progress in olefin polymerization catalyzed by transition metal complexes: new catalysts and new reactions

D Takeuchi - Dalton Transactions, 2010 - pubs.rsc.org
A number of transition metal catalysts including early and late transition metals have been
investigated for olefin polymerization and copolymerization. Progress of the field in this …

1‐Decene oligomerization by new complexes bearing diamine‐diphenolates ligands: Effect of ligand structure

A Hanifpour, N Bahri‐Laleh… - Applied …, 2021 - Wiley Online Library
A series of new titanium (IV) complexes bearing tetradentate diamine‐diphenolates,
homologous to [ONNO] salan type ligands:[Ti {2, 2′‐(OC6H2–4, 6‐tBu2) 2NHC3H6NH}(Cl) …

Fluorinated bis (phenoxyketimine) titanium complexes for the living, isoselective polymerization of propylene: multiblock isotactic polypropylene copolymers via …

JB Edson, Z Wang, EJ Kramer… - Journal of the American …, 2008 - ACS Publications
A series of bis (phenoxyketimine) titanium dichloride complexes were synthesized and
evaluated as catalysts for living, isoselective propylene polymerization upon activation with …

Living olefin polymerization and block copolymer formation with FI catalysts

A Sakuma, MS Weiser, T Fujita - Polymer journal, 2007 - nature.com
This contribution reports on the recent advances in living olefin polymerization catalysis and
block copolymer formation made by fluorinated bis (phenoxy-imine) Ti complexes …

Mechanism of stereospecific polymerization of α-olefins by late-transition metal and octahedral group 4 metal catalysts

M Lamberti, M Mazzeo, D Pappalardo… - Coordination Chemistry …, 2009 - Elsevier
In the last few years remarkable advances have been made in the field of non-
cyclopentadienyl complexes as homogeneous olefin polymerization catalysts. In this paper …

Group 4 complexes of a new [OSSO]-type dianionic ligand. Coordination chemistry and preliminary polymerization catalysis studies

A Cohen, A Yeori, I Goldberg, M Kol - Inorganic chemistry, 2007 - ACS Publications
A straightforward synthesis of a new type of tetradentate dianionic [OSSO]-type ligand is
described. This ligand features an ethylenedithiol core bridged via methylene groups to …

Polymerization of Higher α-Olefins with a Bis(Phenoxyimine)Ti Complex/i-Bu3Al/Ph3CB(C6F5)4:  Formation of Stereo- and Regioirregular High Molecular …

J Saito, Y Suzuki, H Makio, H Tanaka, M Onda… - …, 2006 - ACS Publications
The unique catalytic behavior of a bis (phenoxyimine) Ti complex combined with i-
Bu3Al/Ph3CB (C6F5) 4 (whose active species is a phenoxyamine Ti complex) is discussed …

[PDF][PDF] Same Ligand, Different Metals: Diiodo− Salan Complexes of the Group 4 Triad in Isospecific Polymerization of 1-Hexene and Propylene

AD Cohen, J Kopilov, M Lamberti, V Venditto… - Macromolecules, 2010 - chglib.icp.ac.ru
The design of catalysts that will enable the living polymerization of propylene with high
activities and isoselectivities under ambient conditions remains a challenge in current …