Advances in structurally characterized lanthanide alkoxide, aryloxide, and silyloxide compounds

TJ Boyle, LAM Ottley - Chemical reviews, 2008 - ACS Publications
Often referred to as the “rare earths”, the lanthanide (Ln) elements have gained increased
attention over the past few decades. This has been due to the development of better …

Developments in the coordination chemistry of europium (II)

J Garcia, MJ Allen - European journal of inorganic chemistry, 2012 - Wiley Online Library
Recent advances in the coordination chemistry of Eu2+ are reviewed. Common synthetic
routes for generating discrete Eu2+‐containing complexes reported since 2000 are …

Tetranuclear lanthanide (III) complexes with a zigzag topology from the use of pyridine-2, 6-dimethanol: synthetic, structural, spectroscopic, magnetic and …

DI Alexandropoulos, L Cunha-Silva, L Pham… - Inorganic …, 2014 - ACS Publications
Reaction between Ln (NO3) 3· x H2O (x= 5 or 6) and the potentially tridentate (N, O, O)
chelating/bridging ligand pyridine-2, 6-dimethanol (pdmH2), in the presence of base NEt3 …

Enhancing the Value of Free Metals in the Synthesis of Lanthanoid Formamidinates: Is a Co‐oxidant Needed?

GB Deacon, PC Junk, D Werner - Chemistry–A European …, 2016 - Wiley Online Library
Abstract Treatment of N, N′‐bis (aryl) formamidines (ArFormH), N, N′‐bis (2, 6‐
difluorophenyl) formamidine (DFFormH) or N, N′‐bis (2, 6‐diisopropylphenyl) formamidine …

Direct reaction of iodine-activated lanthanoid metals with 2, 6-di iso propylphenol

S Hamidi, GB Deacon, PC Junk, P Neumann - Dalton Transactions, 2012 - pubs.rsc.org
Rare earth metals activated with ca. 2% iodine react directly with 2, 6-diisopropylphenol
(HOdip) in tetrahydrofuran (thf), 1, 2-dimethoxyethane (dme), and dig–dme (dig= di (2 …

Gas-phase reactions of lanthanide cations with alcohols

JM Carretas, J Marçalo, AP de Matos - International Journal of Mass …, 2004 - Elsevier
The gas-phase reactions of the lanthanide series cations Ln+ (Ln= La–Lu, except Pm) with
methanol, ethanol, and 2-propanol were studied by Fourier transform ion cyclotron …

Hydrocarbon-soluble, polymetallic, lanthanoid aryloxides constructed utilising ligands with distal Bu t groups

GB Deacon, CM Forsyth, R Harika, PC Junk… - Journal of Materials …, 2004 - pubs.rsc.org
The lanthanoid (III) aryloxide complexes [La (OAr) 3 (thf) 3] 2· 5thf (1),[Nd3 (OAr) 9 (thf) 4]·
4thf (2),[Ln (OAr) 3 (thf) 2] 2· 2thf [Ln= Er (3); Yb (4)],[Ln (OAr) 3] n [Ln= Eu (5); Yb (6)],[La4 …

Nanomorphology effects in semiconductors with native ferromagnetism: hierarchical europium (II) oxide tubes prepared via a topotactic nanostructure transition

B Trepka, P Erler, S Selzer, T Kollek, K Boldt… - Advanced …, 2018 - Wiley Online Library
Semiconductors with native ferromagnetism barely exist and defined nanostructures are
almost unknown. This lack impedes the exploration of a new class of materials characterized …

Trivalent lanthanide–alkene complexes: Crystallographic and NMR evidence for coordination of tethered alkenes in the solid state and solution

DJ Berg, T Barclay, X Fei - Journal of Organometallic Chemistry, 2010 - Elsevier
The reaction of 2, 6-diallyl-4-methylphenol (H-DALP) and 2-allyl-4, 6-dimethylphenol (H-
MALP) with Ln [N (SiMe3) 2] 3 affords dimeric {Ln [DALP] 2} 2 [μ-DALP] 2 [Ln= La (3), Ce (4) …

A dinuclear europium (III) complex with thenoyltrifluoroacetonato and 1-(2-pyridylzao)-2-naphtholato ligands and its optical properties

Y Wu, J Wang, X Kong, C Sheng, R Wang… - Inorganica Chimica …, 2011 - Elsevier
Dinuclear lanthanide complexes of the general for Ln2 (TTA) 4 (PAN) 2 (Ln= Eu, Gd, Tb, Yb;
TTA and monodeprotonated thenoyltrifluoroacetone and PAN 1-(2-pyridylazo)-2-naphthol …