[HTML][HTML] An evaluation of corrosion processes affecting copper-coated nuclear waste containers in a deep geological repository

DS Hall, M Behazin, WJ Binns, PG Keech - Progress in Materials Science, 2021 - Elsevier
Permanent disposal of high level nuclear waste in containers that employ steel as a
structural element and copper as a corrosion barrier material is a favoured design concept in …

Probing passivity of corroding metals using scanning electrochemical probe microscopy

SA Skaanvik, SM Gateman - Electrochemical Science …, 2023 - Wiley Online Library
Passive films are essential for the longevity of metals and alloys in corrosive environments.
A great deal of research has been devoted to understanding and characterizing passive …

Effect of sulphide concentration on corrosion behaviors of HVOF-sprayed WC-Cr3C2-Ni and WC-Ni coatings

Z Wei, D Cui, Z Wei, S Hong - … Journal of Refractory Metals and Hard …, 2023 - Elsevier
In this study, the WC-Cr 3 C 2-Ni and WC-Ni coatings were processed on steels with the
HVOF spray, and their corrosion behaviors in 3.5 wt% NaCl solution with 0, 20, 100 and 200 …

[HTML][HTML] Corrosion-induced microstructure degradation of copper in sulfide-containing simulated anoxic groundwater studied by synchrotron high-energy X-ray …

F Zhang, C Örnek, M Liu, T Müller, U Lienert… - Corrosion …, 2021 - Elsevier
Synchrotron high-energy XRD measurements and ab-initio DFT calculations were employed
to investigate microstructural degradation of copper upon exposure to sulfide-containing …

Exploring the governing transport mechanisms of corrosive agents in a Canadian deep geological repository

TL Rashwan, MA Asad, IL Molnar, M Behazin… - Science of The Total …, 2022 - Elsevier
All nuclear energy producing nations face a common challenge associated with the long-
term solution for their used nuclear fuel. After decades of research, many nuclear safety …

Corrosion behaviour of copper under biotic and abiotic conditions in anoxic ground water: Electrochemical study

E Huttunen-Saarivirta, P Rajala, L Carpén - Electrochimica Acta, 2016 - Elsevier
Finnish nuclear waste disposal program proposes to dispose spent nuclear fuel in tightly
sealed copper canisters in a geological repository; here, copper acts as a corrosion barrier …

Passivity breakdown on copper: Influence of temperature

C Dong, F Mao, S Gao, S Sharifi-Asl, P Lu… - Journal of The …, 2016 - iopscience.iop.org
Passivity breakdown and pitting on pure copper has been studied in simulated repository
ground water (x M NaCl+ 2× 10− 4 M Na 2 S, pH= 9.0±0.2 at 40 C, as established by 0.2 M …

The kinetics of film growth and their influence on the susceptibility to pitting of copper in aqueous sulphide solutions

T Martino, J Chen, Z Qin… - Corrosion Engineering …, 2017 - journals.sagepub.com
The formation of copper sulphide films on copper in aqueous sulphide solutions has been
investigated under both natural corrosion and electrochemical conditions. Film growth …

The influence of hydrogen permeation on the protection performance of the Cu coating of nuclear waste containers

X Liu, N Liu, JJ Noël, DW Shoesmith, J Chen, B Hou - Corrosion Science, 2023 - Elsevier
Hydrogen permeation and corrosion behaviour of Cu-coated carbon steel under simulated
nuclear waste disposal conditions of the Beishan area have been investigated. The …

The early-stage corrosion of copper materials in chloride and sulfide solutions: nanoscale characterization and the effect of microstructure

M Guo, K Daub, Q Dong, F Long… - Journal of The …, 2022 - iopscience.iop.org
The microstructures of copper (Cu) materials were investigated by electron backscatter
diffraction, showing that electrodeposited (ED) Cu has a homogenous polycrystalline …