Despite widespread applications of tetravalent cerium compounds in organic synthesis and
catalysis, the coordination and organometallic chemistry of cerium (IV) complexes has not …

A template-free precipitation method was used as a simple and low cost method for
preparation of CeO2 nanoparticles. The structure and morphology of the prepared …

The modification of CeO2 properties by means of aliovalent doping is investigated within the
ab initio density functional theory framework. Lattice parameters, dopant atomic radii, bulk …

Frequency dispersion of high-k dielectrics was observed and classified into two parts:
extrinsic cause and intrinsic cause. Frequency dependence of dielectric constant (dielectric …

The homoleptic pyrazolate complexes [CeIII4 (Me2pz) 12] and [CeIV (Me2pz) 4] 2
quantitatively insert CO2 to give [CeIII4 (Me2pz⋅ CO2) 12] and [CeIV (Me2pz⋅ CO2) 4] …

Cerium-oxo clusters have applications in fields ranging from catalysis to electronics and also
hold the potential to inform on aspects of actinide chemistry. Toward this end, a cerium …

Stable molecular clusters are of interest for targeted deposition in porous materials. In this
work, we report the discovery of two new molecular Ce–O clusters of composition [Ce6O4 …

Reaction of [Ce (NR2) 3](R= SiMe3) with LiNO3 in THF, in the presence of 2, 2, 2-cryptand,
results in the formation of the Ce (III)“ate” complex,[Li (2, 2, 2-cryptand)][Ce (κ2-O2NO)(NR2) …

This work employs density functional theory for calculating the structural, mechanical,
anisotropic, thermal, electronic, and optical properties of Ce 1-x Hf x O 2 (x= 0, 0.25, 0.5, and …

N-Dealkylation of amines by metal oxo intermediates (MO) is related to drug detoxification
and DNA repair in biological systems. In this study, we report the first example of N …