Ethanol-to-butadiene: the reaction and its catalysts

G Pomalaza, PA Ponton, M Capron… - Catalysis Science & …, 2020 - pubs.rsc.org
Butadiene is a crucial chemical, notably for the manufacturing of car tires. The ethanol-to-
butadiene reaction has emerged as a promising solution to both environmental concerns …

Recent advances in catalysts for the conversion of ethanol to butadiene

I Bin Samsudin, H Zhang, S Jaenicke… - Chemistry–An Asian …, 2020 - Wiley Online Library
Butadiene is an important monomer for synthetic rubbers. Currently, the annual demand of∼
16 million tonnes is satisfied by butadiene produced as a byproduct of steam naphtha …

On the deactivation mechanism of zeolite catalyst in ethanol to butadiene conversion

T Yan, L Yang, W Dai, C Wang, G Wu, N Guan… - Journal of …, 2018 - Elsevier
Despite of extensive attention on the ethanol to butadiene (ETB) conversion, the catalyst
deactivation during ETB conversion is rarely investigated and poorly understood. Here, the …

Synthesis of 1, 3-butadiene and its 2-substituted monomers for synthetic rubbers

Y Qi, Z Liu, S Liu, L Cui, Q Dai, J He, W Dong, C Bai - Catalysts, 2019 - mdpi.com
Synthetic rubbers fabricated from 1, 3-butadiene (BD) and its substituted monomers have
been extensively used in tires, toughened plastics, and many other products owing to the …

Reaction Kinetics Analysis of Ethanol Dehydrogenation Catalyzed by MgO–SiO2

HT Abdulrazzaq, A Rahmani Chokanlu… - ACS …, 2020 - ACS Publications
The Mg-catalyzed dehydrogenation of ethanol to yield acetaldehyde is an important step in
the Lebedev reaction. In this work, we prepared a model MgO–SiO2 catalyst by …

Ethanol conversion into 1, 3-butadiene over a mixed Hf-Zn catalyst: Effect of reaction conditions and water content in ethanol

GMC González, P Concepción, ALV Perales… - Fuel Processing …, 2019 - Elsevier
Assessment of catalyst performance is necessary for process design in order to evaluate the
effect of reaction conditions on process economics and configuration. In this work, the …

Effect of ZnO on acid–base properties and catalytic performances of ZnO/ZrO 2–SiO 2 catalysts in 1, 3-butadiene production from ethanol–water mixture

OV Larina, PI Kyriienko, DY Balakin… - Catalysis Science & …, 2019 - pubs.rsc.org
The effect of ZnO and the preparation method of ZnO/ZrO2–SiO2 catalysts on their acid–
base properties and catalytic performances in the conversion of diluted ethanol mixtures into …

ZnTa-TUD-1 as an easily prepared, highly efficient catalyst for the selective conversion of ethanol to 1, 3-butadiene

G Pomalaza, G Vofo, M Capron, F Dumeignil - Green Chemistry, 2018 - pubs.rsc.org
High performances in the conversion of ethanol to 1, 3-butadiene were achieved with a Zn
(II) and Ta (V) catalyst supported on TUD-1, a mesoporous silica. The selectivity reached …

Ethanol conversion into 1, 3-butadiene over a mixed Hf-Zn catalyst: A study of the reaction pathway and catalyst deactivation

GMC González, R Murciano, ALV Perales… - Applied Catalysis A …, 2019 - Elsevier
Some fundamental and practical aspects of a Hf-Zn catalyst, with a nominal composition of
3.0 wt% Hf and 9.3 wt% Zn, and prepared as a physical mixture of Hf/SiO 2 (85 wt%) and the …

One-pot hydrothermal synthesis of multifunctional ZnZrTUD-1 catalysts for highly efficient direct synthesis of butadiene from ethanol

K Wang, L Guo, W Gao, B Zhang, H Zhao… - ACS Sustainable …, 2021 - ACS Publications
The direct conversion of ethanol to butadiene (ETB) is a promising approach for renewable
butadiene production. However, simultaneous achievement of high butadiene selectivity …